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Brut [27]
1 year ago
13

Does a negative ΔH mean that the heat should be treated as a reactant or as a product?

Chemistry
1 answer:
blagie [28]1 year ago
8 0

The negative ΔH mean that the heat should be treated as a reactant or as a product.

<h3>What is thermochemical equation? </h3>

The balanced equation which also include the enthalpy change of the reaction in it is termed as the thermochemical equation.

The change in enthalpy is denoted by ∆H . Depending on the process involved in the chemical equation, the value of ∆H can be negative or positive.

The reaction is said to have enthalpy value of change in enthalpy of a reaction. For instance, the value of ∆H is negative which implies that the reaction is exothermic.

This means that heat is released in the surrounding. Thus, the heat has to be entered in the product side.

Thus, we can say that negative ΔH mean that the heat should be treated as a reactant or as a product.

learn more about thermochemical equation:

brainly.com/question/2733624

#SPJ4

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When performing labratory experiments, which of the following items is ALWAYS necessary to use?
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Consider the following reaction: A(g)⇌2B(g). Find the equilibrium partial pressures of A and B for each of the following differe
Illusion [34]

Answer:

a. Kp=1.4

P_{A}=0.2215 atm

P_{B}=0.556 atm

b.Kp=2.0 * 10^-4

P_{A}=0.495atm

P_{B}=0.00995 atm

c.Kp=2.0 * 10^5

P_{A}=5*10^{-6}atm

P_{B}=0.9999 atm

Explanation:

For the reaction  

A(g)⇌2B(g)

Kp is defined as:

Kp=\frac{(P_{B})^{2}}{P_{A}}

The conditions in the system are:

          A                    B

initial   0                1 atm

equilibrium x       1atm-2x

At the beginning, we don’t have any A in the system, so B starts to react to produce A until the system reaches the equilibrium producing x amount of A. From the stoichiometric relationship in the reaction we get that to produce x amount of A we need to 2x amount of B so in the equilibrium we will have 1 atm – 2x of B, as it is showed in the table.    

Replacing these values in the expression for Kp we get:

Kp=\frac{(1-2x)^{2}}{x}

Working with this equation:

x*Kp=(1-2x)^{2} - -> x*Kp=4x^{2}-4x+1- - >4x^{2}-(4+Kp)*x+1=0

This last expression is quadratic expression with a=4, b=-(4+Kp) and c=1

The general expression to solve these kinds of equations is:

x=\frac{-b(+-)*\sqrt{(b^{2}-4ac)}}{2a} (equation 1)

We just take the positive values from the solution since negative partial pressures don´t make physical sense.

Kp = 1.4

x_{1}=\frac{(1.4+4)+\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=1.128

x_{1}=\frac{(1.4+4)-\sqrt{(-(1.4+4)^{2}-4*4*1)}}{2*4}=0.2215

With x1 we get a partial pressure of:

P_{A}=1.128 atm

P_{B}=1-2*1.128 = -1.256 atm

Since negative partial pressure don´t make physical sense x1 is not the solution for the system.

With x2 we get:

P_{A}=0.2215 atm

P_{B}=1-2*0.2215 = 0.556 atm

These partial pressures make sense so x2 is the solution for the equation.

We follow the same analysis for the other values of Kp.

Kp=2*10^-4

X1=0.505

X2=0.495

With x1

P_{A}=0.505atm

P_{B}=1-2*0.505 = -0.01005 atm

Not sense.

With x2

P_{A}=0.495atm

P_{B}=1-2*0.495 = 0.00995 atm

X2 is the solution for this equation.  

Kp=2*10^5

X1=50001

X2=5*10^{-6}

With x1

P_{A}=50001atm

P_{B}=1-2*50001=-100001atm

Not sense.

With x2

P_{A}= 5*10^{-6}atm

P_{B}=1-2*5*10^{-6}= 0.9999 atm

X2 is the solution for this equation.  

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