Following reaction is involved in above system
HOCl(aq) ↔ H+(aq) + OCl-<span>(aq)
</span>OCl-(aq) + H2O(l) ↔ HOCl(aq) + OH-<span>(aq)
</span>
Now, if the system is obeys 1st order kinetics we have
K = [OCl-][H+<span>]/[HOCl] ............. (1)
</span>∴ [HOCl-] / [OCl-] = [H+] (1 / 3.0 * 10-8<span>) ............. (2)
</span>
and now considering that system is obeying 2nd order kinetics, we have
K = [OH-][HOCl-] / [OCl-] ................. (3<span>)
</span>Subs 2 in 3 we get
K = [OH-][H+] (1 / 3.0 * 10-8<span>)
</span>we know that, [OH-][H+] = 10<span>-14
</span>∴K = 3.3 * 10<span>-7
</span>
Thus, correct answer is e i.e none of these
Answer:- Third choice is correct, 17.6 moles
Solution:- The given balanced equation is:
Al_2(SO_4)_3+6KOH\rightarrow 2Al(OH)_3+3K_2SO_4
We are asked to calculate the moles of potassium hydroxide needed to completely react with 2.94 moles of aluminium sulfate.
From the balanced equation, there is 1:6 mol ratio between aluminium sulfate and potassium hydroxide.
It is a simple mole to mole conversion problem. We solve it using dimensional set up as:
2.94molAl_2(SO_4)_3(\frac{6molKOH}{1molAl_2(SO_4)_3})
= 17.6 mol KOH
So, Third choice is correct, 17.6 moles of potassium hydroxide are required to react with 2.94 moles of aluminium sulfate.
Reaction of dissociation: Ag₂SO₄ → 2Ag⁺ + SO₄²⁻.
m(Ag₂SO₄) = 4 g.
V(Ag₂SO₄) = 1 l.
n(Ag₂SO₄) = m(Ag₂SO₄) ÷ M(Ag₂SO₄).
n(Ag₂SO₄) = 4 g ÷ 311,8 g/mol.
n(Ag₂SO₄) = 0,0128 mol.
n(Ag⁺) = 2 · 0,0128 mol = 0,0256 mol.
n(Ag₂SO₄) = n(SO₄²⁻) = 0,0128 mol.
c(Ag⁺) = n ÷ V = 0,0256 mol ÷ 1 l = 0,0256 mol/l.
Ksp = c(Ag⁺)² · c(SO₄²⁻).
Ksp = (0,0256 mol/l)² · 0,0128 mol/l.
Ksp = 8,3·10⁻⁶.
Thallium has got 81 protons
<u>Have a nice days.......</u>
