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Allushta [10]
1 year ago
7

How do the bonding and antibonding MOs formed from a given pair of AOs compare to each other with respect to:

Chemistry
1 answer:
Ksenya-84 [330]1 year ago
6 0

Bonding MO's have lower energy than antibonding MO's. The bonding MO's lower energy, even lower than its constituent atomic orbitals, accounts for the stability of a molecule in relation to its individual atoms. However, the sum of energy of the MO's must equal the sum of energy of the AO's.

<h3>What is atomic orbital?</h3>

An atomic orbital is a function in atomic theory and quantum mechanics that describes the location and wave-like behavior of an electron in an atom. This formula can be used to calculate the likelihood of locating any atom's electron in any given location surrounding the nucleus. The phrase atomic orbital can also refer to the actual region or place where the electron is projected to be present given the orbital's mathematical form.

Each orbital in an atom is defined by a set of values of the three quantum numbers n, l, and ml, which correspond to the energy, angular momentum, and an angular momentum vector component of the electron, respectively (magnetic quantum number).

To learn more about atomic orbital visit:

brainly.com/question/28240666

#SPJ4

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Two solutions namely, 500 ml of 0.50 m hcl and 500 ml of 0.50 m naoh at the same temperature of 21.6 are mixed in a constant-pre
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24.6 ℃

<h3>Explanation</h3>

Hydrochloric acid and sodium hydroxide reacts by the following equation:

\text{HCl} \; (aq) + \text{NaOH} \; (aq) \to \text{NaCl} \; (aq) + \text{H}_2\text{O} \; (aq)

which is equivalent to

\text{H}^{+} \; (aq) + \text{OH}^{-} \; (aq) \to \text{H}_2\text{O}\; (l)

The question states that the second equation has an enthalpy, or "heat", of neutralization of -56.2 \; \text{kJ}. Thus the combination of every mole of hydrogen ions and hydroxide ions in solution would produce 56.2 \; \text{kJ} or 56.2 \times 10^{3}\; \text{J} of energy.

500 milliliter of a 0.50 mol per liter "M" solution contains 0.25 moles of the solute. There are thus 0.25 moles of hydrogen ions and hydroxide ions in the two 0.500 milliliter solutions, respectively. They would combine to release 0.25 \times 56.2 \times 10^{3} = 1.405 \times 10^{4} \; \text{J} of energy.

Both the solution and the calorimeter absorb energy released in this neutralization reaction. Their temperature change is dependent on the heat capacity <em>C</em> of the two objects, combined.

The question has given the heat capacity of the calorimeter directly.

The heat capacity (the one without mass in the unit) of water is to be calculated from its mass and <em>specific</em> heat.

The calorimeter contains 1.00 liters or 1.00 \times 10^{3} \; \text{ml} of the 1.0 gram per milliliter solution. Accordingly, it would have a mass of 1.00 \times 10^{3} \; \text{g}.

The solution has a specific heat of 4.184 \; \text{J} \cdot \text{g}^{-1} \cdot \text{K}^{-1}. The solution thus have a heat capacity of 4.184 \times 1.00 \times 10^{3} = 4.184 \times 10^{3} \; \text{J} \cdot\text{K}^{-1}. Note that one degree Kelvins K is equivalent to one degree celsius ℃ in temperature change measurements.

The calorimeter-solution system thus has a heat capacity of 4.634 \times 10^{3} \; \text{J} \cdot \text{K}^{-1}, meaning that its temperature would rise by 1 degree celsius on the absorption of 4.634 × 10³ joules of energy. 1.405 \times 10^{4} \; \text{J} are available from the reaction. Thus, the temperature of the system shall have risen by 3.03 degrees celsius to 24.6 degrees celsius by the end of the reaction.

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