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kakasveta [241]
2 years ago
9

Balance the following skeleton reactions and identify the oxidizing and reducing agents:(b) Fe(CN)₆³⁻(aq) + Re(s) →\mathrm{Fe}(\

mathrm{CN})_{6}^{4-}(a q)+\mathrm{ReO}_{4}^{-}(a q) [basic]
Chemistry
1 answer:
photoshop1234 [79]2 years ago
6 0

The given chemical equation is:

Fe(CN)63-(aq) + Re(s)-> Fe(CN)64-(aq) + ReO4-(aq)

Consider oxidation half reaction and balance it first in acidic conditions:

Re-   > ReO4-

Add water on the left side to balance the O-atoms:

Re-  +4H20-  > ReO4-

Add protons on the right side to balance H-atoms:

Re-  +4H20-  > ReO4-+8H+

To balance the charge add electrons:

Re-  +4H20-  > ReO4-+8H+ 7e-------------(1)

Reduction half reaction: Fe(CN)63-(aq) -> Fe(CN)64-(aq)

Add electrons to balance the charge:

Fe(CN)63-(aq) -  +e- > Fe(CN)64- (aq)---------------(2)

Multiply equation(2) with seven :

7{Fe(CN)63-(aq) -  +7e-} > 7{Fe(CN)64- (aq)} ------(3)

Add (1) and (3)

7Fe(CN)63-(aq) -  +7e-} > 7{Fe(CN)64- (aq)}   +   Re-  +4H20-  > ReO4-+8H+ 7e-

Add 8OH- on both sides:7Fe(CN)63-(aq) -  +7e-} > 7{Fe(CN)64- (aq)}   +   Re-  +4H20-   + OH-  > ReO4-+8H+ 7e- +OH-

It becomes:

7Fe(CN)63-(aq)  + rE +8OH-->OH-  >7{Fe(CN)64- +    ReO4-+  4H20

This is the final equation in the basic medium.

Re(s) is oxidised. So it is the reducing agent.

Fe(CN)63- is reduced.It is the oxidising agent.

To know more about skeleton reactions questions

brainly.com/question/24225616

#SPJ4

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The red colour is the limiting reactant.

Red-blue colour ball and two white balls attached together are reactants.

Red-blue colour ball and two white and one red colour ball attached to each other are products.

<h3>What is a limiting reagent?</h3>

The reactant that is entirely used up in a reaction is called a limiting reagent.

A reactant is a substance that is present at the start of a chemical reaction. The substance(s) to the right of the arrow are called products.

A product is a substance that is present at the end of a chemical reaction.

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The red colour is the limiting reactant.

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2 years ago
Which law states that the volume and absolute temperature of a fixed quantity of gas are directly proportional under constant pr
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________ are solutions containing ions that react with acids or bases to minimize their effects.
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What volume of carbon dioxide gas can be collected from
alisha [4.7K]

Answer:

1.22 L of carbon dioxide gas

Explanation:

The reaction that takes place is:

  • CaCO₃ + HCl → CaCl₂ + CO₂ + H₂O

First we <u>determine which reactant is limiting</u>:

  • Calcium carbonate ⇒ 10.0 g CaCO₃ ÷ 100 g/mol = 0.10 mol CaCO₃
  • Hydrochloric acid ⇒ 0.100 L * 0.50 M = 0.05 mol HCl

So HCl is the limiting reactant.

Now we calculate the moles of CO₂ produced:

  • 0.05 mol HCl * \frac{1molCO_{2}}{1molHCl} = 0.05 mol CO₂

Finally we use PV=nRT to <u>calculate the volume</u>:

  • P = 1 atm
  • n = 0.05 mol
  • T = 25 °C ⇒ 25 + 273.16 = 298.16 K

1 atm * V = 0.05 mol * 0.082 atm·L·mol⁻¹·K⁻¹ * 298.16 K

  • V = 1.22 L
7 0
3 years ago
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