Valleys i think !!! possibly
0.1 M x 0.5L = 0.05 mols HCl.
Adding 25 mL 2M NaOH is
2M x 0.025 L = 0.05 mols NaOH.
What you want to do is to back off very slightly with the NaOH (you might try something like 24.95 mL which I calculate to give 0.00019 M or a pH of 3.7. Inching closer, 24.99 mL would leave H^+ of 4E-5 for pH 4.4. The problem here is two-fold.
hope it helps
The Boyle-Mariotte's law or Boyle's law is one of the laws of gases that <u>relates the volume (V) and pressure (P) of a certain amount of gas maintained at constant temperature</u>, as follows:
PV = k
where k is a constant.
We can relate the state of a gas at a specific pressure and volume to another state in which the same gas is at different P and V since the product of both variables is equal to a constant, according to the Boyle's law, which will be the same regardless of the state of the gas. In this way,
P₁V₁ = P₂V₂
Where P₁ and V₁ is the pressure and volume of the gas to a state 1 and P₂ and V₂ is the pressure and volume of the same gas in a state 2.
In this case, in the state 1 the gas occupies a volume V₁ = 100 mL at a pressure of P₁ = 150 kPa. Then, in the state 2 the gas occupies a volume V₂ (that we must calculate through the boyle's law) at a pressure of P₂ = 200 kPa. Substituting these values in the previous equation and clearing V₂, we have,
P₁V₁ = P₂V₂ → V₂ =
→ V₂ = 
→ V₂ = 75 mL
Then, the volume occupied by the gas at 200 kPa is V₂ = 75 mL