Answer:
in the attached image is the reaction mechanism.
Explanation:
The first reaction (reaction 1) shown in the attached image is the Wolff-Kishner reduction, which is characterized when the carbonyl is reduced to an alkane in the presence of a hydrazine and a base. In reaction 1, the aldehyde reacts with hydrazine to produce oxime. This mechanism begins with the attack of the amine on the carbonyl group. Proton exchange happens and the water leaves the molecule.
In reaction 2, the KOH is deprotoned in nitrogen and organized to form the bond between the nitrogen molecule. this deprotonation releases the nitrogen gas
Answer: 2NOBr(g) ⇌ 2NO(g) + Br2(g)
Explanation: For volume changes in equillibrium, the following are to be taken into consideration:
- Volume changes have no effect on equillibrium system that contains solid or aqueous solutions.
- An increase in volume of an equilibrium system will shift to favor the direction that produces more moles of gas.
- A decrease in volume of an equilibrium system will shift to favor the direction that produces less moles of gas.
- Volume changes will have no effect on the equillibrium system if there is an equal number of moles on both sides of the reaction.
2NOBr(g) ⇌ 2NO(g) + Br2(g) is the equillibrium system because there are more moles of products,therefore an increase in the volume of the reaction will shift to the right and produce more moles of products. Also both reactants and products exist in the gaseous state and does not have equal number of moles.
The rate of disappearance of chlorine gas : 0.2 mol/dm³
<h3>Further explanation</h3>
The reaction rate (v) shows the change in the concentration of the substance (changes in addition to concentrations for reaction products or changes in concentration reduction for reactants) per unit time.
For reaction :
The rate reaction :
![\tt -\dfrac{1}{a}\dfrac{d[-A]}{dt}= -\dfrac{1}{b}\dfrac{d[-B]}{dt}=\dfrac{1}{c}\dfrac{d[C]}{dt}=\dfrac{1}{d}\dfrac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctt%20-%5Cdfrac%7B1%7D%7Ba%7D%5Cdfrac%7Bd%5B-A%5D%7D%7Bdt%7D%3D%20-%5Cdfrac%7B1%7D%7Bb%7D%5Cdfrac%7Bd%5B-B%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bc%7D%5Cdfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%5Cdfrac%7B1%7D%7Bd%7D%5Cdfrac%7Bd%5BD%5D%7D%7Bdt%7D)
Reaction for formation CCl₄ :
<em>CH₄+4Cl₂⇒CCl₄+4HCl</em>
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From equation, rate of reaction = rate of formation CCl₄ = 0.05 mol/dm³
Rate of formation of CCl₄ = reaction rate x coefficient of CCCl₄
0.05 mol/dm³ = reaction rate x 1⇒reaction rate = 0.05 mol/dm³
The rate of disappearance of chlorine gas (Cl₂) :
Rate of disappearance of Cl₂ = reaction rate x coefficient of Cl₂
Rate of disappearance of Cl₂ = 0.05 x 4 = 0.2 mol/dm³
The quantum mechanical model is used to describe the energy and most likely location of an electron.
Answer: Option A
<u>Explanation:
</u>
The quantum mechanical model leads to the introduction of quantum numbers representing the energy levels, sub-shells, orbitals as well as spin states of the electrons. So according to the quantum numbers we can perfectly define the position and energy of any electron in an element.
According to Pauli’s principle, any two electron cannot be having same set of quantum numbers. So, using the principle quantum number, azimuthal quantum number, magnetic and spin quantum number, we can define the energy and location of an electron in the atom.
