2. what volume of 0.0150-m hcl solution is required to titrate 150. ml of a 0.0100-m ca(oh)2 solution? (10 points)
1 answer:
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A electrochemical reaction is said to be spontaneous, if 
Answer 1:
Consider reaction: <span>Ni^2+ (aq) + S^2- (aq) ----> + Ni (s) + S (s)
The cell representation of above reaction is given by;
</span>
Hence,
we know that,
and
Therefore,
= - 0.25 - (-0.47) = 0.22 v
Since, is positive, hence cell reaction is spontaneous
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Answer 2:
Consider reaction: <span>Pb^2+ (aq) +H2 (g) ----> Pb (s) +2H^+ (aq)
</span>
The cell representation of above reaction is given by;
Hence,
we know that,
and
Therefore, = - 0.126 - 0 = -0.126 v
Since, is negative, hence cell reaction is non-spontaneous.
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Answer 3:
Consider reaction: <span>2Ag^+ (aq) + Cr(s) ---> 2 Ag (s) +Cr^2+ (aq)
</span>
The cell representation of above reaction is given by;
Hence,
we know that,
and
Therefore, = - 0.22 - (-0.913) = 0.693 v
Since, is positive, hence cell reaction is spontaneous
Answer 1:
Consider reaction: <span>Ni^2+ (aq) + S^2- (aq) ----> + Ni (s) + S (s)
The cell representation of above reaction is given by;
</span>
Hence,
we know that,
and
Therefore,
Since,
.....................................................................................................................
Answer 2:
Consider reaction: <span>Pb^2+ (aq) +H2 (g) ----> Pb (s) +2H^+ (aq)
</span>
The cell representation of above reaction is given by;
Hence,
we know that,
and
Therefore,
Since,
....................................................................................................................
Answer 3:
Consider reaction: <span>2Ag^+ (aq) + Cr(s) ---> 2 Ag (s) +Cr^2+ (aq)
</span>
The cell representation of above reaction is given by;
Hence,
we know that,
and
Therefore,
Since,
The protons of methylene group between the two carbonyl groups in ethylacetoacetate are acidic in nature. When compounds containing such acidic protons are treated with bases the loose proton and form enolates.
In this particular example when ethylacetoacetate is reacted with methyl magnesium bromide, the methyl group abstracts the acidic proton and converts into methane gas. The enolate when hydrolyzed is again converted into ethylacetoacetate as shown below,
In this particular example when ethylacetoacetate is reacted with methyl magnesium bromide, the methyl group abstracts the acidic proton and converts into methane gas. The enolate when hydrolyzed is again converted into ethylacetoacetate as shown below,