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aivan3 [116]
3 years ago
10

The following system is at equilibrium:

Chemistry
1 answer:
Delvig [45]3 years ago
3 0

Answer:

1) No shift

2) No shift

3) Leftward shift

4)Rightward sifht

Explanation:

1) 2) Adding N or Removing N in the equilibrium will produce No shift, because of its solid state, the N is not contemplated in the equilibrium equation:

K=\frac{[L]^2}{[M]^3}

3) Increasing the volume produces a decrase in the preassure due to the expansion of the gases. This will cause a leftward shift, because the system will try to increase the moles of gas and in consecuence of this, also increase the preassure.

4) Decreasing the volume has the opposite effect of the item 3): the preassure will increase and the system will consume moles of gas to decrease it, producing a rightward shift.

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A gas mixture with 4 mol of Ar, x moles of Ne, and y moles
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Answer:

a) \Delta G_{mixing}=\frac{R*T}{12}*[4*ln (1/3) +x*ln (x/12) +(8-x)*ln ((8-x)/12)]

b) x=4

c) \Delta G_{max}=-2721.9 J/mol

Explanation:

Gas mixture:

n_{Ar}= 4 mol

n_{Ne}= x mol

n_{Xe}= y mol

n_{tot}= n_{Ar} + n_{Ne} + n_{Xe}=3*n_{Ar}

n_{Ne} + n_{Xe}=2*n_{Ar}

x + y=8 mol

y=8 mol- x

Mol fractions:

x_{Ar}=\frac{4 mol}{12 mol}=1/3

x_{Ne}=\frac{x mol}{12 mol}=x/12

x_{Xe}=\frac{8 - x mol}{12 mol}=(8-x)/12

Expression of \Delta G_{mixing}

\Delta G_{mixing}=R*T*\sum_{i]*x_i*ln (x_i)

\Delta G_{mixing}=R*T*[1/3*ln (1/3) +x/12*ln (x/12) +(8-x)/12*ln ((8-x)/12)]

\Delta G_{mixing}=\frac{R*T}{12}*[4*ln (1/3) +x*ln (x/12) +(8-x)*ln ((8-x)/12)]

Expression of \Delta G_{max}

\frac{d \Delta G_{mixing}}{dx}=0

\frac{d \Delta G_{mixing}}{dx}=\frac{R*T}{12}*[ln (x/12)+12-ln ((8-x)/12)-12]

0=\frac{R*T}{12}*[ln (x/12)-ln ((8-x)/12)

0=[ln (x/12)-ln ((8-x)/12)

ln (x/12)=ln ((8-x)/12)

x=(8-x)

x=4

\Delta G_{max}=\frac{8.314*298}{12}*[4*ln (1/3) +4*ln (4/12) +(8-4)*ln ((8-4)/12)]

\Delta G_{max}=\frac{8.314*298}{12}*[4*ln (1/3) +4*ln (1/3) +(4)*ln (1/3)]

\Delta G_{max}=\frac{8.314*298}{12}*[12*ln (1/3)]

\Delta G_{max}=-2721.9 J/mol

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