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Akimi4 [234]
1 year ago
8

If the energy difference between two electronic states is 214.68 kJ / mol , calculate the frequency of light emitted when an ele

ctron drops from higher to lower state. Planck's constant , h = 39.79 × 1/10¹⁴ kJ sec per mol .​
Chemistry
1 answer:
atroni [7]1 year ago
5 0

{\qquad\qquad\huge\underline{{\sf Answer}}}

Here we go ~

Energy difference btween the two electronic states can be expressed as :

{ \qquad \sf  \dashrightarrow \: \Delta E = h\nu}

[ h = planks constant,{\: \nu }= frequency ]

\qquad \sf  \dashrightarrow \:214.68 = 39.79 \times 10 {}^{ - 14}  \times  \nu

\qquad \sf  \dashrightarrow \: \nu =  \cfrac{214.68}{39.79 \times 10 {}^{ - 4} }

\qquad \sf  \dashrightarrow \: \nu =  \cfrac{214.68}{39.79 }  \times 10 {}^{14}

\qquad \sf  \dashrightarrow \: \nu  \approx  5.395 \times10 {}^{14}  \:\:hertz

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Following are the answer to this question:

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NH_3    \ \ \ \ \ \ \ \     + H^{+}  \ \ \ \ \ \ \longrightarrow NH_4^{+}                    

I (m)       0.033(m)            0.025                       0.04166

C            -0.025                 -0.025                       + 0.025  

E            8.3\times 10^{-3}     0                    0.0667

now calculating pH:

when ph= 8.83:

P^{H}= p^{kb}|+ \log\frac{[NH_4^{+}]}{[NH_3]}\\\\8.83=p^{kb}+\log\frac{0.0667}{8.3 \times 10^{-3}}\\\\p^{kb}=8.83-0.9069\\\\ \ \ \ =7.7231 \\\\\ The P^{kb} \ for \ NH_3 \ is =7.7231\\\\\ The P^{kb} \ for N^{+}H_4=14-7.7231\\\\\ \ \ \ \ \ =6.2769

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