According to this formula:
(P1V1) / T1 = (P2V2) / T2
convert T from C° to Kelvin:
T1 = 83 + 273 = 356 K
T2= 96 + 273 = 369 K
convert P from torr to atm:
1 torr = 0.00131578947 atm<span>
p1 = 0.839474 atm
P2 = 1.415789 atm
By substitution in the previous formula:
(0.839474 x 10.6 ) / (356) = ( 1.415789 x V2 ) / 369
So:
V2 = 6.5 L</span>
Chemical change...................
Answer:
(a) -0.00017 M/s;
(b) 0.00034 M/s
Explanation:
(a) Rate of a reaction is defined as change in molarity in a unit time, that is:

Given the following reaction:

We may write the rate expression in terms of reactants firstly. Since reactants are decreasing in molarity, we're adding a negative sign. Similarly, if we wish to look at the overall reaction rate, we need to divide by stoichiometric coefficients:
![r = -\frac{\Delta [N_2O_5]}{2 \Delta t}](https://tex.z-dn.net/?f=r%20%3D%20-%5Cfrac%7B%5CDelta%20%5BN_2O_5%5D%7D%7B2%20%5CDelta%20t%7D)
Reaction rate is also equal to the rate of formation of products divided by their coefficients:
![r = \frac{\Delta [NO_2]}{4 \Delta t} = \frac{\Delta [O_2]}{\Delta t}](https://tex.z-dn.net/?f=r%20%3D%20%5Cfrac%7B%5CDelta%20%5BNO_2%5D%7D%7B4%20%5CDelta%20t%7D%20%3D%20%5Cfrac%7B%5CDelta%20%5BO_2%5D%7D%7B%5CDelta%20t%7D)
Let's find the rate of disappearance of the reactant firstly. This would be found dividing the change in molarity by the change in time:

(b) Using the relationship derived previously, we know that:
![-\frac{\Delta [N_2O_5]}{2 \Delta t} = \frac{\Delta [NO_2]}{4 \Delta t}](https://tex.z-dn.net/?f=-%5Cfrac%7B%5CDelta%20%5BN_2O_5%5D%7D%7B2%20%5CDelta%20t%7D%20%3D%20%5Cfrac%7B%5CDelta%20%5BNO_2%5D%7D%7B4%20%5CDelta%20t%7D)
Rate of appearance of nitrogen dioxide is given by:
![r_{NO_2} = \frac{\Delta [NO_2]}{\Delta t}](https://tex.z-dn.net/?f=r_%7BNO_2%7D%20%3D%20%5Cfrac%7B%5CDelta%20%5BNO_2%5D%7D%7B%5CDelta%20t%7D)
Which is obtained from the equation:
![-\frac{\Delta [N_2O_5]}{2 \Delta t} = \frac{\Delta [NO_2]}{4 \Delta t}](https://tex.z-dn.net/?f=-%5Cfrac%7B%5CDelta%20%5BN_2O_5%5D%7D%7B2%20%5CDelta%20t%7D%20%3D%20%5Cfrac%7B%5CDelta%20%5BNO_2%5D%7D%7B4%20%5CDelta%20t%7D)
If we multiply both sides by 4, that is:
![-\frac{4 \Delta [N_2O_5]}{2 \Delta t} = \frac{\Delta [NO_2]}{\Delta t}](https://tex.z-dn.net/?f=-%5Cfrac%7B4%20%5CDelta%20%5BN_2O_5%5D%7D%7B2%20%5CDelta%20t%7D%20%3D%20%5Cfrac%7B%5CDelta%20%5BNO_2%5D%7D%7B%5CDelta%20t%7D)
This yields:
[tex]r_{NO_2} = \frac{\Delta [NO_2]}{\Delta t} = -2\frac{\Delta [N_2O_5]}{ \Delta t} = -2\cdot (-0.00017 M/s) = 0.00034 M/s[tex]
Answer:
An ideal gas is a theoretical gas composed of many randomly moving point particles that are not subject to interparticle interactions. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics.
Answer: The balanced equation for overall reaction is:
(CH3)3AuPH3 ----> C2H6 + (CH3)AuPH3
Explanation:
The reaction mechanism is given as follows:
Step 1: (CH3)3AuPH3 ↔ (CH3)3Au + PH3 (fast)
Step 2: (CH3)3Au → C2H6 + (CH3)Au (slow)
Step 3: (CH3)Au + PH3 → (CH3)AuPH3 (fast)
To balance this equation, firstly, we conduct proper atom count for each steps of the reaction mechanism.
It is important to note that for a reaction that involves several steps, the rate law is normally derived from the slow step ( which is step2 from the above mechanism).
Therefore, the balanced chemical equation for the overall reaction is:
(CH3)3AuPH3 ----> C2H6 + (CH3)AuPH3