A solution contains 0.10 m sodium cyanide and 0.10 m potassium hydroxide. solid zinc acetate is added slowly to this mixture. wh
at is the formula of the substance that precipitates first?
1 answer:
1) Zn(CH₃COO)₂(s) + 2KOH(aq) = Zn(OH)₂(s) + 2CH₃COOK(aq)
Ksp{Zn(OH)₂}=1.2*10⁻¹⁷
2) Zn(CH₃COO)₂(s) + 2NaCN(aq) = Zn(CN)₂(s) + 2CH₃COONa(aq)
Ksp{Zn(CN)₂}=2.6*10⁻¹³
Ksp{Zn(OH)₂}<Ksp{Zn(CN)₂}
Zn(OH)₂ precipitates first
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