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vovangra [49]
3 years ago
11

4. When benzene reacts with 1-chloro-2,2-dimethylpropane (neopentyl chloride) in the presence of aluminum chloride, the major pr

oduct is 2-methyl-2-phenylbutane, not 2,2-dimethyl-1- phenylpropane (neopentylbenzene). Explain this result

Chemistry
1 answer:
BARSIC [14]3 years ago
8 0

Answer:

Explanation:

In this case, we have a <u>Friedel-Craft reaction</u> (see figure 1). Usually in this type of reaction, the benzene ring is <u>bonded directly to the carbon that has the halide atom</u>. But in this specific case, this is not happening.

To understand why we have to remember the reaction mechanism of this reaction. As first, step the Cl-C bond attacks the AlCl_3 and we form a new bond between the alkyl halide and the AlCl_3, finally the C-Cl bond is broken and a <u>carbocation is formed</u>. In this case, we will have a primary carbocation, a very <u>unstable species</u>. Therefore we will have a <u>methyl shift</u> to obtain a tertiary carbocation.

This tertiary carbocation will react with and continues the reaction. (See figure 2)

I hope it helps!

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3 years ago
In which groups of the modern periodic table are very active metals and very active non-metals placed?​
eimsori [14]

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2 years ago
If 3.289 x 10^23 atoms of potassium react with excess water, how many grams of hydrogen gas would be produced?
GarryVolchara [31]

Answer:

The amount in grams of hydrogen gas produced is 0.551 grams

Explanation:

The parameters given are;

Number of atoms of potassium, aₙ = 3.289 × 10²³ atoms

Chemical equation for the reaction is given as follows;

2K + 2H₂O \rightarrow KOH + H₂

Avogadro's number, N_A, regarding the number of molecules or atom per mole is given s follows;

N_A = 6.02 × 10²³ atoms/mole

Therefore;

The number of moles of potassium present = 3.289 × 10²³/(6.02 × 10²³) = 0.546 moles

2 moles of potassium produces one mole of hydrogen gas, therefore;

1 moles of potassium produces 1/2 mole of hydrogen gas, and 0.546 moles of potassium will produce 0.546/2 moles of hydrogen which is 0.273 moles of hydrogen gas

The molar mass of hydrogen gas = 2.016 grams

Therefore, 0.273 moles will have a mass of 0.273×2.016 = 0.551 grams.

The amount in grams of hydrogen gas produced = 0.551 grams.

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3 years ago
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The pH scale is used to measure the degree of acidity or alkalinity of a solution. The scale runs from 0 (very acidic solutions can have a negative pH) to 14 (very alkaline solutions can have a pH higher than this), while a neutral liquid such as pure water has a pH of 7. The pH is linked to the concentration of hydrogen ions (H +) in the solution. Diluting an acid or alkali affects the concentration of H +<span> ions in a solution and therefore affects the pH. In this activity, we will investigate how diluting an acid or alkali affects the pH.
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