Answer: Option D is correct.
Explanation: Equation given by de Broglie is:

where,
= wavelength of the particle
h = Planck's constant
m = mass of the particle
v = velocity of the particle
In option A, football will have some mass and is moving with a velocity of 25 m/s, hence it will have some wavelength.
In Option B, unladen swallow also have some mass and is moving with a velocity of 38 km/hr, hence it will also have some wavelength.
In Option C, a person has some mass and is running with a velocity of 7 m/hr, hence it will also have some wavelength.
As, the momentum of these particles are large, therefore the wavelength will be of small magnitude and hence, is not observable.
From the above, it is clearly visible that all the options are having some wavelength, so option D is correct.
Answer:
This tells us the radial velocity of the object and that the object is approaching or coming towards us.
Explanation:
Certain chemicals radiate with particular wavelengths or colors when their temperature is raised or when they are charged electrically. Also observable are dark strokes separating the spectrum known as absorption lines
These spectral lines of chemicals are well known as stated above and from the phenomenon of Doppler effect, spectroscopy can be used to detect the movement of a distant object by the change of the emitted frequency of the wavelength
The Doppler effect is used in calculating the radial velocity of a distant object due to the fact that an approaching object compresses its emitted signal wavelength while a receding object has a longer wavelength than normal
I think it would be C.100.5cm or D.100.5ml hope that helps