<u>Given information:</u>
Concentration of HCl = 0.035 M
<u>To determine:</u>
pH of the solution
<u>Explanation:</u>
Hydrochloric acid, HCl is a strong acid. It will completely dissociate to give H+ and Cl- ions
HCl → H+ + Cl-
Hence the concentration of H+ = Cl- = 0.035M
Now, pH measures the strength of H+ ions in a given solution. It is expressed as:
pH = -log[H+]
pH (HCl) = -log(0.035) = 1.46
Ans: pH of 0.035M HCl is 1.46
Answer: Option (d) is the correct answer.
Explanation:
Steps involved for the given reaction will be as follows.
Step 1:
(fast)
Rate expression for step 1 is as follows.
Rate = k ![[NO]^{2}](https://tex.z-dn.net/?f=%5BNO%5D%5E%7B2%7D)
Step 2: 
This step 2 is a slow step. Hence, it is a rate determining step.
Step 3.
(fast)
Here,
is intermediate in nature.
All the steps are bimolecular and it is a second order reaction. Also, there is no catalyst present in this reaction.
Thus, we can conclude that the statement step 1 is the rate determining step, concerning this mechanism is not directly supported by the information provided.
Percent error (%)= 
Accepted value is true value.
Measured values is calculated value.
In the question given Accepted value (true value) = 63.2 cm
Given Measured(calculated values) = 63.1 cm , 63.0 cm , 63.7 cm
1) Percent error (%) for first measurement.
Accepted value (true value) = 63.2 cm, Measured(calculated values) = 63.1 cm
Percent error (%)= 



Percent error = 0.158 %
2) Percent error (%) for second measurement.
Accepted value (true value) = 63.2 cm, Measured(calculated values) = 63.0 cm
Percent error (%)= 



Percent error = 0.316 %
3) Percent error (%) for third measurement.
Accepted value (true value) = 63.2 cm, Measured(calculated values) = 63.7 cm
Percent error (%)= 




Percent error = 0.791 %
Percent error for each measurement is :
63.1 cm = 0.158%
63.0 cm = 0.316%
63.7 cm = 0.791%
<h2>

=
![\dfrac{[H^{+}] [A^{-}]}{[HA]}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5BH%5E%7B%2B%7D%5D%20%5BA%5E%7B-%7D%5D%7D%7B%5BHA%5D%7D)
</h2>
Explanation:
- When an aqueous solution of a certain acid is prepared it is dissociated is as follows-
⇄ 
Here HA is a protonic acid such as acetic acid, 
- The double arrow signifies that it is an equilibrium process, which means the dissociation and recombination of the acid occur simultaneously.
- The acid dissociation constant can be given by -
= ![\dfrac{[H^{+}] [A^{-}]}{[HA]}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5BH%5E%7B%2B%7D%5D%20%5BA%5E%7B-%7D%5D%7D%7B%5BHA%5D%7D)
- The reaction is can also be represented by Bronsted and lowry -
⇄ ![[H_3O^+] [A^-]](https://tex.z-dn.net/?f=%5BH_3O%5E%2B%5D%20%5BA%5E-%5D)
- Then the dissociation constant will be
= ![\dfrac{[H_3O^{+}] [A^{-}]}{[HA]}](https://tex.z-dn.net/?f=%5Cdfrac%7B%5BH_3O%5E%7B%2B%7D%5D%20%5BA%5E%7B-%7D%5D%7D%7B%5BHA%5D%7D)
Here,
is the dissociation constant of an acid.
Answer:
1) The power of Niagara Falls is 1.176 × 10⁹ W
2) The number of 15 W LED light bulbs it could power is 78.4 × 10⁶ light bulbs
Explanation:
1) The Niagara falls water mass flow rate = 2,400,000 kg/s
The height of the fall = 50 meters
The gravitational potential energy = Mass (kg) × height (m) × gravity (9.8 m/s²)
The power = The energy converted per second = Mass flow rate (kg/s) × height (m) × gravity (9.8 m/s²)
Therefore;
The power of Niagara Falls= 2,400,000 kg/s × 50 m ×9.8 m/s²= 1.176 × 10⁹ W
The power of Niagara Falls = 1.176 × 10⁹ W
2) The number, n, of 15 W LED light bulbs it could power is given by the relation;
n × 15 W = 1.176 × 10⁹ W
∴ n = 1.176 × 10⁹ W/(15 W) = 78.4 × 10⁶ light bulbs
The number of 15 W LED light bulbs it could power = 78.4 × 10⁶ light bulbs.