The structure of this oligopeptide is attached:
It consists of arginine - alanine - phenylalanine and leucine
From the picture we can see that N terminus charge is +1
Also Arginine is considered as basic amino acid with charge +1
C terminus charge is -1
At pH = 8, the whose pKa are less than pH will be deprotonated and the net charge will be +1
So the net charge of this oligopeptide is +1 at pH = 8
Answer:
194.6 mL of SO₂
Explanation:
The reaction that takes place is:
P₄S₃ + 6O₂(g) → P₄O₁₀ + 3SO₂(g)
<u>To solve this problem we need to use PV=nRT</u>, so first let's convert the given units:
- 23.8 °C → 23.8 + 273.15 = 296.95 K
- 747 torr → 747/760 = 0.983 atm
We need to calculate V, so in order to do that we calculate n, using the mass of the reactant (P₄S₃):
0.576 g P₄S₃ *
= 7.85 * 10⁻³ mol SO₂ = n
PV=nRT
0.983 atm * V = 7.85 * 10⁻³ mol * 0.082 atm·L·mol⁻¹·K⁻¹ * 296.95 K
V = 0.1946 L
- Finally we convert L into mL:
0.1946 * 1000 = 194.6 mL
Complete one rotation.
Hope this helps.
Answer:
see explanation below
Explanation:
First to all, this is a redox reaction, and the reaction taking place is the following:
2KMnO4 + 3H2SO4 + 5H2O2 -----> 2MnSO4 + K2SO4 + 8H2O + 5O2
According to this reaction, we can see that the mole ratio between the peroxide and the permangante is 5:2. Therefore, if the titration required 21.3 mL to reach the equivalence point, then, the moles would be:
MhVh = MpVp
h would be the hydrogen peroxide, and p the permanganate.
But like it was stated before, the mole ratio is 5:2 so:
5MhVh = 2MpVp
Replacing moles:
5nh = 2MpVp
Now, we just have to replace the given data:
nh = 2MpVp/5
nh = 2 * 1.68 * 0.0213 / 5
nh = 0.0143 moles
Now to get the mass, we just need the molecular mass of the peroxide:
MM = 2*1 + 2*16 = 34 g/mol
Finally the mass:
m = 0.0143 * 34
m = 0.4862 g
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