I think what '13C' means is the isotope of carbon with mass number of 13. Its mass is 13 amu. The unit amu is equivalent to g/mol. The average atomic mass of Carbon is actually 12. But since we are solving for this particular isotope, we use a molar mass of 13 g/mol.
2 g C-13 * 1 mol/13 g = 0.154 moles of C-13
Answer: The molecular formula will be 
Explanation:
Mass of C= 49.47 g
Mass of N = 28.85 g
Mass of O = 16.48 g
Mass of H = 5.20 g
Step 1 : convert given masses into moles.
Moles of C =
Moles of N =
Moles of O =
Moles of H =
Step 2 : For the mole ratio, divide each value of moles by the smallest number of moles calculated.
For C = 
For N =
For O =
For H =
The ratio of C : N: O: H = 4: 2: 1: 5
Hence the empirical formula is
The empirical weight of
= 4(12)+2(14)+1(16)+5(1)= 97 g.
The molecular weight = 194.19 g/mole
Now we have to calculate the molecular formula.
The molecular formula will be = 
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H-C≡C-H this is the lewis structure of acetylene
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