Colorful flowers and blueberrie looking ones and the trees
Answer:
[CO] = 0.078M
[Cl2] = 0.078M
[COCl2] = 0.477M
Explanation:
Based on the reaction:
CO(g) Cl2(g) ⇄ COCl2(g)
<em>Where equilibrium constant, kc, is:</em>
kc = 77.5 = [COCl2] / [CO] [Cl2]
[] represents the equilibrium concentration of each gas. The initial concentration of each gas is:
[CO] = 0.555mol/1.00L = 0.555M
[Cl2] = 0.555M
And equilibrium concentrations are:
[CO] = 0.555M - x
[Cl2] = 0.555M - x
[COCl2] = x
<em>Where x is reaction coordinate</em>
Replacing in kc expression:
77.5 = [x] / [0.555M - x] [0.555M - x]
77.5 = x / 0.308025 - 1.11 x + x²
23.8719 - 86.025 x + 77.5 x² = x
23.8719 - 87.025 x + 77.5 x² = 0
x = 0.477M. Right answer
x = 0.646M. False answer. Produce negative concentrations
Replacing:
<h3>[CO] = 0.555M - 0.477M = 0.078M</h3><h3>[Cl2] = 0.078M</h3><h3>[COCl2] = 0.477M</h3>
And those concentrations are the equilibrium concentrations
Answer:
-2.3 ºC
Explanation:
Kf (benzene) = 5.12 ° C kg mol – 1
1st - We calculate the moles of condensed gas using the ideal gas equation:
n = PV / (RT)
P = 748/760 = 0.984 atm
T = 270 + 273.15 = 543.15 K
V = 4 L
R = 0.082 atm.L / mol.K
n = (0.984atm * 4L) / (0.082atm.L / K.mol * 543.15K) = 0.088 mol
Then, you calculate the molality of the solution:
m = n / kg solvent
m = 0.088 mol / 0.058 kg = 1.52mol / kg
Then you calculate the decrease in freezing point (DT)
DT = m * Kf
DT = 1.52 * 5.12 = 7.8 ° C
Knowing that the freezing point of pure benzene is 5.5 ºC, we calculate the freezing point of the solution:
T = 5.5 - 7.8 = -2.3 ºC
