<u>Answer:</u> The tree was burned 16846.4 years ago to make the ancient charcoal
<u>Explanation:</u>
The equation used to calculate rate constant from given half life for first order kinetics:

where,
= half life of the reaction = 5715 years
Putting values in above equation, we get:

Rate law expression for first order kinetics is given by the equation:
![k=\frac{2.303}{t}\log\frac{[A_o]}{[A]}](https://tex.z-dn.net/?f=k%3D%5Cfrac%7B2.303%7D%7Bt%7D%5Clog%5Cfrac%7B%5BA_o%5D%7D%7B%5BA%5D%7D)
where,
k = rate constant = 
t = time taken for decay process = ? yr
= initial amount of the sample = 100 grams
[A] = amount left after decay process = 13 grams
Putting values in above equation, we get:

Hence, the tree was burned 16846.4 years ago to make the ancient charcoal
Do you know what is meant by needed? does it mean lone pairs?
This chemical reaction can also be written as
2C2H6+7O2-->4CO2+6H2O
This is a chemical reaction because reactants are converted into products. This is the combustion of ethane where ethane and oxygen have been converted into carbon dioxide and water