Explanation:
Let the volume of the solution be 100 ml.
As the volume of glycol = 50 = volume of water
Hence, the number of moles of glycol = 
= 
= 
= 0.894 mol
Hence, number of moles of water = 
= 2.77
As glycol is dissolved in water.
So, the molality = 
= 17.9
Therefore, the expected freezing point = 
= 
Thus, we can conclude that the expected freezing point is .
Answer:
= 0.134; 
= 0.866
The partial pressure of isopropanol = 34.04 Torr; The partial pressure of propanol = 5.26 Torr
Explanation:
For each of the solutions:
mole fraction of isopropanol (
) = 1 - mole fraction of propanol (
).
Given: mole fraction of propanol = 0.247. Thus, the mole fraction of isopropanol = 1 - 0.247 = 0.753.
Furthermole, the partial pressure of isopropanol = *vapor pressure of isopropanol = 0.753*45.2 Torr = 34.04 Torr
The partial pressure of propanol = *vapor pressure of propanol = 0.247*20.9 Torr = 5.16 Torr
Similarly,
In the vapor phase,
The mole fraction of propanol () = 
Where, 
is the partial pressure of propanol and 
is the partial pressure of isopropanol.
Therefore,
= 5.26/(34.04+5.16) = 0.134
= 1 - 0.134 = 0.866
What of the gasses is N and the flame changes it's color from Orange to blue
