Answer:

Explanation:
Firstly, write the expression for the equilibrium constant of this reaction:
![K_{eq} = \frac{[ADP][Pi]}{ATP}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BADP%5D%5BPi%5D%7D%7BATP%7D)
Secondly, we may relate the change in Gibbs free energy to the equilibrium constant using the equation below:

From here, rearrange the equation to solve for K:

Now we know from the initial equation that:
![K_{eq} = \frac{[ADP][Pi]}{ATP}](https://tex.z-dn.net/?f=K_%7Beq%7D%20%3D%20%5Cfrac%7B%5BADP%5D%5BPi%5D%7D%7BATP%7D)
Let's express the ratio of ADP to ATP:
![\frac{[ADP]}{[ATP]} = \frac{[Pi]}{K_{eq}}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BADP%5D%7D%7B%5BATP%5D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7BK_%7Beq%7D%7D)
Substitute the expression for K:
![\frac{[ADP]}{[ATP]} = \frac{[Pi]}{K_{eq}} = \frac{[Pi]}{e^{-\frac{\Delta G^o}{RT}}}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BADP%5D%7D%7B%5BATP%5D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7BK_%7Beq%7D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7Be%5E%7B-%5Cfrac%7B%5CDelta%20G%5Eo%7D%7BRT%7D%7D%7D)
Now we may use the values given to solve:
![\frac{[ADP]}{[ATP]} = \frac{[Pi]}{K_{eq}} = \frac{[Pi]}{e^{-\frac{\Delta G^o}{RT}}} = [Pi]e^{\frac{\Delta G^o}{RT}} = 1.0 M\cdot e^{\frac{-30 kJ/mol}{2.5 kJ/mol}} = 6.14\cdot 10^{-6}](https://tex.z-dn.net/?f=%5Cfrac%7B%5BADP%5D%7D%7B%5BATP%5D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7BK_%7Beq%7D%7D%20%3D%20%5Cfrac%7B%5BPi%5D%7D%7Be%5E%7B-%5Cfrac%7B%5CDelta%20G%5Eo%7D%7BRT%7D%7D%7D%20%3D%20%5BPi%5De%5E%7B%5Cfrac%7B%5CDelta%20G%5Eo%7D%7BRT%7D%7D%20%3D%201.0%20M%5Ccdot%20e%5E%7B%5Cfrac%7B-30%20kJ%2Fmol%7D%7B2.5%20kJ%2Fmol%7D%7D%20%3D%206.14%5Ccdot%2010%5E%7B-6%7D)
A second-order extension of the Kohn-Sham total energy in density-functional theory (DFT) with respect to charge density fluctuations serves as the foundation for the density functional based tight binding (DFTB) approach.
What is DFTB method?
- The density functional based tight binding (DFTB) electronic structure method was used to study the clusters of bare TiO2 and TiO2 with linked organic ligands modeling polyorganic composites used as photocatalytic materials.
- The results were compared to those obtained from B3LYP/6-31G(d,p) calculations, semiempirical methods PM6 and PM7, and available experimental data.
- It was discovered that the highly scalable DFTB approach produces outcomes that are nearly on the level of theory B3LYP/6-31G(d,p).
- The trans3d set more accurately reproduces the energies of the composite material production in polycondensation processes, but the corrected version of the tiorg DFTB parameter set (tiorg-smooth) performs better for structural parameter estimations.
- The tiorg-smooth and trans3d settings perform better than the matsci set in some way. Studies of adsorption complexes of bare TiO2 clusters can be conducted using the tiorg-smooth and matsci sets.
Learn more about the Density with the help of the given link:
brainly.com/question/23487480
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It is photosynthesis
<span>
photosynthesis is the process by which green plants and some other organisms use sunlight to synthesize foods from carbon dioxide and water. photosynthesis in plants generally involves the green pigment chlorophyll and generates oxygen as a byproduct, hope it helps</span>
Explanation:
The rest of the energy is passed on as food to the next level of the food chain. The figure at the left shows energy flow in a simple food chain. Notice that at each level of the food chain, about 90% of the energy is lost in the form of heat.