Answer: d) The volume occupied by the molecules themselves is no longer negligible. This most be the answer because a, b and c don't make any sense at all.
Explanation:
Answer:
[Cu²⁺] = 2.01x10⁻²⁶
Explanation:
The equilibrium of Cu(CN)₄²⁻ is:
Cu²⁺ + 4CN⁻ ⇄ Cu(CN)₄²⁻
And Kf is defined as:
Kf = 1.0x10²⁵ = [Cu(CN)₄²⁻] / [Cu²⁺] [CN⁻]⁴
As Kf is too high you can assume all Cu²⁺ is converted in Cu(CN)₄²⁻ -Cu²⁺ is limiting reactant-, the new concentrations will be:
[Cu²⁺] = 0
[CN⁻] = 0.33M - 4×2.2x10⁻³ = 0.3212M
[Cu(CN)₄²⁻] = 2.2x10⁻³
Some [Cu²⁺] will be formed and equilibrium concentrations will be:
[Cu²⁺] = X
[CN⁻] = 0.3212M + 4X
[Cu(CN)₄²⁻] = 2.2x10⁻³ - X
<em>Where X is reaction coordinate</em>
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Replacing in Kf equation:
1.0x10²⁵ = [2.2x10⁻³ - X] / [X] [0.3212M +4X]⁴
1.0x10²⁵ = [2.2x10⁻³ - X] / 0.0104858X + 0.524288 X² + 9.8304 X³ + 81.92 X⁴ + 256 X⁵
1.04858x10²³X + 5.24288x10²⁴ X² + 9.8304x10²⁵ X³ + 8.192x10²⁶ X⁴ + 2.56x10²⁷ X⁵ = 2.2x10⁻³ - X
1.04858x10²³X + 5.24288x10²⁴ X² + 9.8304x10²⁵ X³ + 8.192x10²⁶ X⁴ + 2.56x10²⁷ X⁵ - 2.2x10⁻³ = 0
Solving for X:
X = 2.01x10⁻²⁶
As
[Cu²⁺] = X
<h3>[Cu²⁺] = 2.01x10⁻²⁶</h3>
H^+ = acid
OH^- = alkaline
Acids have a pH of below 7. The lower the number, the strongest the acid.
Answer:
Temperature, mass, and the type of material are factors that affect the thermal energy of an object.
Material with the higher specific heat will have more thermal energy than material with lower specific heat if they both have the same mass and temperature.
