Answer:
See explanation.
Explanation:
Since potassium tert-butoxide is a strong bulky base, we expect that an elimination reaction predominates.
This reaction is expected to occur by E2 mechanism. The cis isomer of 1-bromo-4-tert-butylcyclohexane is known to react faster by E2 mechanism because it fulfills the anticoplanar arrangement required for for E2 mechanism, where the leaving group and adjacent proton must be anti to each other and in the same plane. The trans isomer can not fulfill this requirement.
The answer is B
Explanation:
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Ookay
1) T
2) T
3) F
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Answer:
a): not necessarily due to London Dispersion Forces and dipole-dipole interactions.
b): not necessarily due to London Dispersion Forces.
Explanation:
There are three major types of intermolecular interaction:
- Hydrogen bonding between molecules with H-O, H-N, or H-F bonds and molecules with lone pairs.
- Dipole-dipole interactions between all molecules.
- London dispersion forces between all molecules.
The melting point of a substance is a result of all three forces, combined.
Note that the more electrons in each molecule, the stronger the London Dispersion Force. Generally, that means the more atoms in each molecule, the stronger the London dispersion force. The strength of London dispersion force between large molecules can be surprisingly strong.
For example,
(water) molecules are capable of hydrogen bonding. The melting point of
at
is around
. That's considerably high when compared to other three-atom molecules.
In comparison, the higher alkane hexadecane (
, straight-chain) isn't capable of hydrogen bonding. However, under a similar pressure, hexadecane melts at around
above the melting point of water. The reason is that with such a large number of atoms (and hence electrons) per molecule, the London dispersion force between hexadecane molecules could well be stronger than that the hydrogen bonding between water molecules.
Similarly, the dipole moments in HCl (due to the highly-polar H-Cl bonds) are much stronger than those in hexadecane (due to the C-H bonds.) However, the boiling point of hexadecane under standard conditions is much higher (at around
than that of HCl.