The correct option is C.
An atom can be either in the ground state or in an excited state. An atom is said to be in the ground state, if the total energy of its electron can not be lowered by moving one or more electrons into different orbitals. At the ground state, the electrons in the atom have the lowest energy possible and they are stable. On the other hand, an atom is said to be in an excited state, if the energy of its electrons can be lowered by transferring one or more electrons into different orbitals. An atom in an excited state has more energy and is less stable.
According to what is known about chemical equilibrium and Le Chatelier's principle, when you increase the amount of the reactants, the reaction will be moved to the products, this is because, the most reactants we have the most products we can produce.
From the given choices, the one that goes according to this reason is the third one: The volume of water vapor increases.
Answer : The value of new volume is, 50.0 mL
Explanation :
Boyle's Law : It is defined as the pressure of the gas is inversely proportional to the volume of the gas at constant temperature and number of moles.

or,

where,
= initial pressure at STP = 1 atm
= final pressure = 4.00 atm
= initial volume at STP = 200.0 mL
= final volume = ?
Now put all the given values in the above equation, we get:


Therefore, the value of new volume is, 50.0 mL