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ioda
3 years ago
6

Why does a solution of a weak base and its conjugate acid act as a better buffer than does a solution?

Chemistry
1 answer:
german3 years ago
7 0
Hello!

A solution of a weak base and its conjugate acid act as a better buffer than does a solution of a weak base alone because <span>A solution of a weak base alone has no acid present to absorb added base.</span> 

If an acid (In this case HCl) is added to a buffer or a weak base solution, the following reaction happens:

HCl + A⁻ → HA + Cl⁻

In this way, the addition of acid is neutralized by the base.

If a base is added (In this case NaOH), only a solution of a weak base and its conjugate acid can react in the following way:

NaOH + HA → NaA + H₂O

So, a solution of only a weak base can resist the addition of acids but not bases, so it isn't a good buffer. 

Have a nice day!
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Which of these substances has the lowest pH? 0.5 M HBr, pOH = 13.5 0.05 M HCl, pOH = 12.7 0.005 M KOH, pOH = 2.3
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<h3><u>Answer;</u></h3>

0.5 M HBr, pOH = 13.5 ; Has the lowest pH

<h3><u>Explanation;</u></h3>

From the question;

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or pH = 14 - pOH

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pH = - log [H+]

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Norfenefrine (C₈H₁₁NO₂).

<h3>Further explanation</h3>

We will solve a case related to one of the colligative properties, namely freezing point depression.

The freezing point of the solution is the temperature at which the solution begins to freeze. The difference between the freezing point of the solvent and the freezing point of the solution is called freezing point depression.

\boxed{ \ \Delta T_f = T_f(solvent) - T_f(solution) \ } \rightarrow \boxed{ \ \Delta T_f = K_f \times molality \ }

<u>Given:</u>

A mysterious white powder could be,

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When 82 mg of the powder is dissolved in 1.50 mL of ethanol (density = 0.789 g/cm³, normal freezing point −114.6°C, Kf = 1.99°C/m), the freezing point is lowered to −115.5°C.

<u>Question: </u>What is the identity of the white powder?

<u>The Process:</u>

Let us identify the solute, the solvent, initial, and final temperatures.

  • The solute = the powder
  • The solvent = ethanol
  • The freezing point of the solvent = −114.6°C
  • The freezing point of the solution = −115.5°C

Prepare masses of solutes and solvents.

  • Mass of solute = 82 mg = 0.082 g
  • Mass of solvent = density x volume, i.e., \boxed{ \ 0.789 \ \frac{g}{cm^3} \times 1.50 \ cm^3 = 1.1835 \ g = 0.00118 \ kg  \ }

We must prepare the solvent mass unit in kg because the unit of molality is the mole of the solute divided by the mass of the solvent in kg.

The molality formula is as follows:

\boxed{ \ m = \frac{moles \ of \ solute}{kg \ of \ solvent} \ } \rightarrow \boxed{ \ m = \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

Now we combine it with the formula of freezing point depression.

\boxed{ \ \Delta T_f =  K_f \times \frac{mass \ of \ solute \ (g)}{molar \ mass \ of \ solute \times kg \ of \ solvent} \ }

It is clear that we will determine the molar mass of the solute (denoted by Mr).

We enter all data into the formula.

\boxed{ \ -114.6^0C - (-115.5^0C) = 1.99 \frac{^0C}{m} \times \frac{0.082 \ g}{Mr \times 0.00118 \ kg} \ }

\boxed{ \ 0.9 = \frac{1.99 \times 0.082}{Mr \times 0.00118} \ }

\boxed{ \ Mr = \frac{0.16318}{0.9 \times 0.00118} \ }

We get \boxed{ \ Mr = 153.65 \ }

These results are very close to the molar mass of norfenefrine which is 153.18 g/mol. Thus the white powder is norfenefrine.

<h3>Learn more</h3>
  1. The molality and mole fraction of water brainly.com/question/10861444
  2. About the mass and density of ethylene glycol as an  antifreeze brainly.com/question/4053884
  3. About the solution as a homogeneous mixture  brainly.com/question/637791

Keywords: a mysterious white powder, sugar, cocaine, codeine, norfenefrine, fructose, the solute, the solvent, dissolved, ethanol, normal freezing point, the freezing point depression, the identity

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