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lianna [129]
3 years ago
10

An aqueous antifreeze solution is 40.0% ethylene glycol (C2H6O2) by mass. The density of the solution is 1.75 g/cm3. Calculate t

he molality, molarity, and mole fraction of the ethylene glycol.
Chemistry
1 answer:
photoshop1234 [79]3 years ago
3 0

Answer:

Xm ethylene glycol = 0.16

Molality = 10.75 m

Molarity = 11.3M

Explanation:

40.0% by mass. This data says that 40 g of ethyelen glycol are contained in 100 g of solution

Therefore: Mass of solute is 40g

Mass of solvent = 60 g

Mass of solution = 100 g

We convert the mass to moles → 40 g . 1mol / 62 g = 0.645 moles

We convert the solvent mass to moles → 60 g . 1mol /18g = 3.33 moles

Xm ethylene glycol = Moles of ethylene glycol / Total moles

0.645 / (0.645 + 3.33) = 0.16

Molality are the moles of solute in 1kg of solvent.

We convert the mass of solvent to kg → 60 g . 1kg/1000g = 0.060kg

Molality (mol/kg) = 0.645 mol /0.060kg = 10.75 m

To determine molarity we use the density of solution in order to find out the volume: density = mass / volume

1.75 g/cm³ = 100 g / volume → 100 g / 1.75 g/cm³ = 57.1 cm³  (1cm³ = 1ml)

We convert the solution's volume to L → 57.1 mL . 1L/1000mL = 0.0571L

Molarity → moles of solute in 1L of solution

Molarity (mol/L) → 0.645 mol / 0.0571L = 11.3M

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Answer:

(a)  0.72 lbm· ft/s²

(b)  20.3 kPa,  2.94 lbf / in²

(c)  98.6 ºF,  310 K

(d)  1.5 x 10⁻² J,  6.1 x 10⁻² cal

Explanation:

Our strategy here will be to find the conversion factors for the quantities we are asked in each part, and perform the calculations.

(a) 10,000 dynes to lbm ·ft/s²

here we are asked to convert  the  force of 10,000 dynes to lbm ·ft/s². Recall that F= ma ( m= mass, a = acceleration), thus

10,000 dynes = 10 g cm/s²

converting the force

10,000 g cm/s² x (1 lbm/454 g) x (1 ft / 30.48 cm ) /s² = 0.72 lbm· ft/s²

(b)

1 atm = 101.33 pa

0.2 atm x ( 101.33 kPa ) = 20.3 kPa

1 atm = 14.7 lbf / in²

0.2 atm x ( 14.7 lbf / in² /atm ) = 2.94 lbf / in²

(c) The formula for the conversion from ºC to ºF is:

ºF = 9/5 ºC +32

ºF = 9/5 ( 37ºC) + 32 = 98.6 ºF

K = ºC + 273

K = (37 + 273) K = 310 K

(d) 50 in²·lbm/s² to joules and calories

Since the unit in² ·lbm/s² is not that common, lets convert it using their definition.

These are energy units, and we know the energy is the force times distance. In turn force is mass times acceleration so that the units of energy are mass time distance per time squared.

Joules is the unit of energy  in the metric system.

50 in² lbm/s² = 50 in²x ( 2.54 cm/in x 1m /100cm)² x (1lbm x 0.454 Kg/lbm)/s²

= 1.5 x 10⁻² Kg m²/² =  1.5 x 10⁻² J

To convert to cal it wilñl be easier to use the value in joules just calculated:

1.5 x 10⁻² J x  (4.184 cal/J) = 6.1 x 10⁻² cal

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