Answer:
300K.
Explanation:
The following data were obtained from the question:
Initial volume (V1) = 300L
Initial temperature (T1) = 200K
Final volume (V2) = 450L
Final temperature (T2) =..?
Since the pressure is constant, the gas is obeying Charles' law.
Using the Charles' law equation, we can obtain the new temperature of the gas as follow:
V1/T1 = V2/T2
300/200 = 450/T2
Cross multiply to express in linear form
300 x T2 = 200 x 450
Divide both side by 300
T2 = (200 x 450)/ 300
T2 = 300K
Therefore, the new temperature of the gas is 300K.
Answer:
V = 22.34 L
Explanation:
Given data:
Volume of O₂ needed = ?
Temperature and pressure = standard
Number of molecules of water produced = 6.0× 10²³
Solution:
Chemical equation:
2H₂ + O₂ → 2H₂O
Number of moles of water:
1 mole contain 6.022× 10²³ molecules
6.0× 10²³ molecules × 1 mole / 6.022× 10²³ molecules
0.99 mole
Now we will compare the moles of oxygen and water.
H₂O : O₂
2 : 1
0.996 : 0.996
Volume of oxygen needed:
PV = nRT
V = nRT/P
V = 0.996 mol × 0.0821 atm.L/mol.K × 273.15 K / 1 atm
V = 22.34 L
Answer :
(a) The average rate will be:
![\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D%3D9.36%5Ctimes%2010%5E%7B-5%7DM%2Fs)
(b) The average rate will be:
![\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D%3D1.87%5Ctimes%2010%5E%7B-4%7DM%2Fs)
Explanation :
The general rate of reaction is,

Rate of reaction : It is defined as the change in the concentration of any one of the reactants or products per unit time.
The expression for rate of reaction will be :
![\text{Rate of disappearance of A}=-\frac{1}{a}\frac{d[A]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20A%7D%3D-%5Cfrac%7B1%7D%7Ba%7D%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of B}=-\frac{1}{b}\frac{d[B]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20B%7D%3D-%5Cfrac%7B1%7D%7Bb%7D%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D)
![\text{Rate of formation of C}=+\frac{1}{c}\frac{d[C]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20C%7D%3D%2B%5Cfrac%7B1%7D%7Bc%7D%5Cfrac%7Bd%5BC%5D%7D%7Bdt%7D)
![\text{Rate of formation of D}=+\frac{1}{d}\frac{d[D]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20D%7D%3D%2B%5Cfrac%7B1%7D%7Bd%7D%5Cfrac%7Bd%5BD%5D%7D%7Bdt%7D)
![Rate=-\frac{1}{a}\frac{d[A]}{dt}=-\frac{1}{b}\frac{d[B]}{dt}=+\frac{1}{c}\frac{d[C]}{dt}=+\frac{1}{d}\frac{d[D]}{dt}](https://tex.z-dn.net/?f=Rate%3D-%5Cfrac%7B1%7D%7Ba%7D%5Cfrac%7Bd%5BA%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7Bb%7D%5Cfrac%7Bd%5BB%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7Bc%7D%5Cfrac%7Bd%5BC%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7Bd%7D%5Cfrac%7Bd%5BD%5D%7D%7Bdt%7D)
From this we conclude that,
In the rate of reaction, A and B are the reactants and C and D are the products.
a, b, c and d are the stoichiometric coefficient of A, B, C and D respectively.
The negative sign along with the reactant terms is used simply to show that the concentration of the reactant is decreasing and positive sign along with the product terms is used simply to show that the concentration of the product is increasing.
The given rate of reaction is,

The expression for rate of reaction :
![\text{Rate of disappearance of }Br^-=-\frac{1}{5}\frac{d[Br^-]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DBr%5E-%3D-%5Cfrac%7B1%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of }BrO_3^-=-\frac{d[BrO_3^-]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DBrO_3%5E-%3D-%5Cfrac%7Bd%5BBrO_3%5E-%5D%7D%7Bdt%7D)
![\text{Rate of disappearance of }H^+=-\frac{1}{6}\frac{d[H^+]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20disappearance%20of%20%7DH%5E%2B%3D-%5Cfrac%7B1%7D%7B6%7D%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D)
![\text{Rate of formation of }Br_2=+\frac{1}{3}\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20%7DBr_2%3D%2B%5Cfrac%7B1%7D%7B3%7D%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
![\text{Rate of formation of }H_2O=+\frac{1}{3}\frac{d[H_2O]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20formation%20of%20%7DH_2O%3D%2B%5Cfrac%7B1%7D%7B3%7D%5Cfrac%7Bd%5BH_2O%5D%7D%7Bdt%7D)
Thus, the rate of reaction will be:
![\text{Rate of reaction}=-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{d[BrO_3^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}=+\frac{1}{3}\frac{d[H_2O]}{dt}](https://tex.z-dn.net/?f=%5Ctext%7BRate%20of%20reaction%7D%3D-%5Cfrac%7B1%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D%3D-%5Cfrac%7Bd%5BBrO_3%5E-%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7B6%7D%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7B3%7D%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7B3%7D%5Cfrac%7Bd%5BH_2O%5D%7D%7Bdt%7D)
<u>Part (a) :</u>
<u>Given:</u>
![\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D%3D1.56%5Ctimes%2010%5E%7B-4%7DM%2Fs)
As,
![-\frac{1}{5}\frac{d[Br^-]}{dt}=+\frac{1}{3}\frac{d[Br_2]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D%3D%2B%5Cfrac%7B1%7D%7B3%7D%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D)
and,
![\frac{d[Br_2]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D%3D%5Cfrac%7B3%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D)
![\frac{d[Br_2]}{dt}=\frac{3}{5}\times 1.56\times 10^{-4}M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D%3D%5Cfrac%7B3%7D%7B5%7D%5Ctimes%201.56%5Ctimes%2010%5E%7B-4%7DM%2Fs)
![\frac{d[Br_2]}{dt}=9.36\times 10^{-5}M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BBr_2%5D%7D%7Bdt%7D%3D9.36%5Ctimes%2010%5E%7B-5%7DM%2Fs)
<u>Part (b) :</u>
<u>Given:</u>
![\frac{1}{5}\frac{d[Br^-]}{dt}=1.56\times 10^{-4}M/s](https://tex.z-dn.net/?f=%5Cfrac%7B1%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D%3D1.56%5Ctimes%2010%5E%7B-4%7DM%2Fs)
As,
![-\frac{1}{5}\frac{d[Br^-]}{dt}=-\frac{1}{6}\frac{d[H^+]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D%3D-%5Cfrac%7B1%7D%7B6%7D%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D)
and,
![-\frac{1}{6}\frac{d[H^+]}{dt}=\frac{3}{5}\frac{d[Br^-]}{dt}](https://tex.z-dn.net/?f=-%5Cfrac%7B1%7D%7B6%7D%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D%3D%5Cfrac%7B3%7D%7B5%7D%5Cfrac%7Bd%5BBr%5E-%5D%7D%7Bdt%7D)
![\frac{d[H^+]}{dt}=\frac{6}{5}\times 1.56\times 10^{-4}M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D%3D%5Cfrac%7B6%7D%7B5%7D%5Ctimes%201.56%5Ctimes%2010%5E%7B-4%7DM%2Fs)
![\frac{d[H^+]}{dt}=1.87\times 10^{-4}M/s](https://tex.z-dn.net/?f=%5Cfrac%7Bd%5BH%5E%2B%5D%7D%7Bdt%7D%3D1.87%5Ctimes%2010%5E%7B-4%7DM%2Fs)
Gas is the correct answer