The answer is because they are magnetic B.
Answer:
Option A
Explanation:
Addition of too much of solvent will make the solution dilute due to which the crystals will not form. Hence option D is incorrect
On the other hand adding a minimum amount of boiling solvent will give a saturated solution for recrystallization. Hence, option A is incorrect
Addition of cold solvent will lower the rate of formation of crystals. Hence, both option B and C are incorrect
Given:
0.060 mol of NiC2O4
Ksp = 4 x 10⁻¹⁰
1.0 L of solution
Kf of Ni(NH3)6 2⁺ = 1.2 x 10⁹
<span>NiC2O4 + 6NH3 ⇋ Ni(NH3)6 2+ + 2O4 2- </span>
<span>NiC2O4 ⇋ Ni 2+ + C2O4 2- ...Ksp </span>
<span>Ni2+ + 6NH3 ⇋ Ni(NH3)6 2+...Kf </span>
Ksp * Kf = (4 x 10⁻¹⁰) * (1.2 x 10⁹) = 0.48
K = 0.48 = [Ni(NH3)6 2+][C2O4 2-] / [NH3]⁶<span>
</span>0.48 = (0.060)² / [NH3]⁶<span> ... (dissolved C2O4 2- = 0.060M)
</span><span>[NH3]</span>⁶<span> = (0.060)</span>²<span> / 0.48 = </span>0.0036 / 0.48 = 0.0075
NH3 = ⁶√0.0075
NH3 = 0.44 M
True is the correct answer
