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svlad2 [7]
3 years ago
10

During diffusion which way do the substances move?

Chemistry
1 answer:
ser-zykov [4K]3 years ago
3 0
During diffusion substances move from the denser medium (meaning where there is more of the substance) to less dense medium (meaning where there is less of the substance).


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(1) The solubility of Salt AB2(S) IS 5mol/dm^3.
Svetlanka [38]

Answer:

a. Ksp = 4s³

b. 5.53 × 10⁴ mol³/dm⁹

Explanation:

a. Obtain an expression for the solubility product of AB2(S),in terms of s.

AB₂ dissociates to give

AB₂ ⇄ A²⁺ + 2B⁻

Since 1 mole of AB₂ gives 1 mole of A and 2 moles of B, we have the mole ratio as

AB₂ ⇄ A²⁺ + 2B⁻

1 : 1 : 2

Since the solubility of AB₂ is s, then the solubility of A is s and that of B is 2s

So, we have

AB₂ ⇄ A²⁺ + 2B⁻

[s]        [s]    [2s]

So, the solubility product Ksp = [A²⁺][B⁻]²

= (s)(2s)²

= s(4s²)

= 4s³

b. Calculate the Ksp of AB₂, given that solubility is 2.4 × 10³ mol/dm³

Given that the solubility of AB is 2.4 × 10³ mol/dm³ and the solubility product Ksp = [A²⁺][B⁻]² = 4s³ where s = solubility of AB = 2.4 × 10³ mol/dm³

Substituting the value of s into the equation, we have

Ksp = 4s³

= 4(2.4 × 10³ mol/dm³)³

= 4(13.824 × 10³ mol³/dm⁹)

= 55.296 × 10³ mol³/dm⁹

= 5.5296 × 10⁴ mol³/dm⁹

≅ 5.53 × 10⁴ mol³/dm⁹

Ksp = 5.53 × 10⁴ mol³/dm⁹

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Consider the following reaction at constant P. Use the information here to determine the value of ΔSsurr at 355 K. Predict wheth
Elena-2011 [213]

Answer:

\Delta S_{surr} = + 0.32113\: kJ/K

Explanation:

Given: Entropy of surrounding: ΔSsurr = ?

Temperature: T= 355 K

The change in enthalpy of reaction: ΔH = -114 kJ

Pressure: P = constant

As we know, ΔH = -114 kJ ⇒ negative

Therefore, the given reaction is an exothermic reaction

Therefore, Entropy of surrounding at <em>constant pressure</em> is given by,

\Delta S_{surr} = \frac{-\Delta H}{T}

\therefore \Delta S_{surr} = -\left (\frac{-114 kJ}{355 K}  \right ) = + 0.32113\: kJ/K > 0

<u><em>In the given reaction:</em></u>

2NO(g) + O₂(g) → 2NO₂(g)

As, the number of moles of gaseous products is less than the number of moles of gaseous reactants.

\therefore \Delta S_{system} <  0

As we know, <em>for a spontaneous process, that the total entropy should be positive.</em>

\Delta S_{total} = \Delta S_{surr} + \Delta S_{system} > 0  

<u>Therefore, at the given temperature,</u>

  • if \Delta S_{surr} > \Delta S_{system} \Rightarrow \Delta S_{total} > 0 then the given reaction is spontaneous
  • if \Delta S_{surr} < \Delta S_{system} \Rightarrow \Delta S_{total} < 0 then the given reaction is non-spontaneous
6 0
4 years ago
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