The balanced equation for the reaction is
CO(g) + 2H₂(g) ⇄ CH₃<span>OH(g)
Since given concentrations are at equilibrium state, the expression for the equilibrium constant, k can be written as
k = [</span>CH₃OH(g)] / [CO(g)] [H₂(g) ]²
By substitution,
k = 0.030 M / 0.020 M x (<span>0.072 M</span>)²
k = 289.35 M⁻²
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We need the diagram to answer the question
Answer : The time passed in years is 
Explanation :
Half-life of carbon-14 = 5730 years
First we have to calculate the rate constant, we use the formula :



Now we have to calculate the time passed.
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = 
t = time passed by the sample = ?
a = initial amount of the reactant disintegrate = 15.3
a - x = amount left after decay process = 14.8
Now put all the given values in above equation, we get


Therefore, the time passed in years is 