Answer:
involuntary, attached to the eyeball, nonstriated.
Explanation:
The change in energy of the system : -63 J
<h3>Further explanation</h3>
Given
279 J work
216 J heat
Required
The change in energy
Solution
Laws of thermodynamics 1
ΔU=Q+W
Rules :
- receives heat, Q +
- releases heat, Q -
- work is done by a system, W -
- work is done on a system, W +
a gas work on the surrounding : W =-279 J
a gas absorb heat from surrounding : Q = +216 J
Internal energy :
= -279+216
= -63 J
Answer : The value of rate constant is, 
Explanation :
First we have to calculate the rate constant, we use the formula :
Expression for rate law for first order kinetics is given by:

where,
k = rate constant = ?
t = time passed by the sample = 20 min
a = let initial amount of the reactant = 100 g
a - x = amount left after decay process = 100 - 85 = 15 g
Now put all the given values in above equation, we get


Therefore, the value of rate constant is, 