Answer:
After the solution is heated, but before additional solute is added
Explanation:
An unsaturated solution is a solution that contains less solute than it can normally hold at a given temperature. Hence an unsaturated solution can still dissolve more solute.
When the solution is heated, the saturated cold solution becomes an unsaturated hot solution which is capable of dissolving more solute at this point.
Once more solute is dissolved, the solution becomes saturated again just before it begins to cool since no more solute dissolves in the solution at some point before cooling and addition of seed crystals.
Answer:
19.8 kg of C₂H₂ is needed
Explanation:
We solve this by a rule of three:
If 1251 kJ of heat are relased in the combustion of 1 mol of acetylene
95.5×10⁴ kJ of heat may be released by the combustion of
(95.5×10⁴ kJ . 1) /1251kJ = 763.4 moles of C₂H₂
Let's convert the moles to mass → 763.4 mol . 26 g/1 mol = 19848 g
If we convert the mass from g to kg → 19848 g . 1kg / 1000g = 19.8 kg
Answer:
ΔH rxn = -1010 kJ/molC₂H₂
Explanation:
To obtain the enthalpy change for a reaction from bond energies what we do is to make an inventory of the bonds broken and formed for the balanced chemical reaction:
C₂H₂ + 5/2O₂ ⇒ 2CO₂ + H₂O
Bond Broken Bonds Formed
2 C-H + 1 C≡C + 5/2 O=O 4C=O + 2 H-O
Enthalpy bonds broken:
2 mol (456 kJ/mol)+ 1 mol (962 kJ/mol) + 5/2 mol (499 kJ/mol) = 3121.5 kJ
Enthalpy bond formed:
4 mol (802 kJ/mol) + 2 mol (462 kJ/mol) = 4132.0 kJ
ΔH rxn = H broken - H formed = 3121.5 kJ - 4132.0 kJ = - 1010 kJ (per mol C₂H₂ )
If the dehydration reaction of an alcohol is successful. The changes would be seen in the IR spectrum for the product compared to the starting material are as,
- The O-H and C-O band is disappear from stating material
- The addition of a C-C double bond band in the product.
In dehydration reaction of alcohol ( O-H and C-O bond ) contain , the water molecule (
) is release from the reactant and C-C double bond is form which is known as alkene in the product .
The reactant and product have different structure. To determine the structure of the compound IR spectroscopy is used. In IR spectrum the peak corresponds to 3400-3600 cm is missing in the product of dehydration reaction of an alcohol. It means O-H band is disappear from stating material.
learn about IR SPECTRUM
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