Some atoms are exceptions to the octet rule by having an expanded octet. Which characteristic is needed for an atom to have an e
xpanded octet?
A.The atom has empty d-orbitals.
B.The atom has more than eight valence electrons before bonding.
C.The atom has empty p-orbitals.
D.The atom has fewer than eight valence electrons after bonding
A.The atom has empty d-orbitals.
B.The atom has more than eight valence electrons before bonding.
C.The atom has empty p-orbitals.
D.The atom has fewer than eight valence electrons after bonding
2 answers:
Answer: The correct option would be A.
Explanation: The main group elements which make more bonds than that was predicted from the octet rule are supposed to have expanded octet.
These elements tend to have more than 8 valence electrons after bonding and this can be achieved when we have empty d-orbitals.
When we have empty p-orbitals, total number of valence electrons than can be occupied will be 8.
Electronic configuration when valence shell's empty p-orbitals are fully filled =
which means that a total of 8 electrons can be occupied which does not satisfy expanded octet rule.
Example of molecule showing expanded octet rule is given in the image. Here, after bonding Phosphorous has 10 electrons which is occupied in empty d-orbitals.
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Answer:
The mole fraction of N₂ is 0.26.
Explanation:
The pressure exerted by a particular gas in a mixture is known as its partial pressure. So, Dalton's law states that the total pressure of a gas mixture is equal to the sum of the pressures that each gas would exert if it were alone:
PT = PA + PB
This relationship is due to the assumption that there are no attractive forces between the gases.
Dalton's partial pressure law can also be expressed in terms of the mole fraction of the gas in the mixture. The mole fraction is a dimensionless quantity that expresses the ratio of the number of moles of a component to the number of moles of all the components present.
So in a mixture of two or more gases, the partial pressure of gas A can be expressed as:
PA = XA * PT
In this case:
- PA= PN₂= 300 torr
- XA=XN₂= ?
- PT= 1.50 atm= 1140 torr (being 1 atm= 760 torr)
Replacing:
300 torr= XN₂*1140 torr
Solving:
XN₂= 0.26
<u><em>The mole fraction of N₂ is 0.26.</em></u>