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Pie
2 years ago
7

The rate constant for the second-order reaction !s 0. 54 m-1 s-1 at 300°c. how long (in seconds) would 1t take for the concentra

tion of n02 to decrease from 0. 62 m to 0. 28 m?
Chemistry
1 answer:
Jlenok [28]2 years ago
3 0

The answer is 3.63. seconds.

Second order reaction is the reaction in which the rate of reaction depends on either the concentration of two reactant species or on the two times the concentration of single reactant species.

What is the integrated rate law for the second-order reaction?

  • The integrated rate law that relates the concentration, time and rate constant for the second-order reaction is:

\frac{1}{[A]} =\frac{1}{[A]_{0} } +kt

Where

\[\begin{array}{l}{\rm{[A]  -  concentration\ of\ reactant\ A\ at\ time\ t}}\\{{\rm{[A]}}_0}{\rm{ -  initial\ concentration\ of\ reactant\ A}}\\{\rm{t - time}}\\{\rm{k  -  rate\ constant}}\end{array}\]

  • Now, in the given question,

k = 0.54 m^{-1}. s^{-1}

[NO_{2} ]= 0.62\ M

[NO_{2} ]_{0} = 0.28\ M

  • Thus, using the rate law, the time is calculated as-

\frac{1}{0.28\ M} =\frac{1}{0.62\ M } +(0.54 m^{-1}.s^{-1})  t\\\\(0.54 m^{-1}.s^{-1})  t= \frac{1}{0.28\ M} -\frac{1}{0.62\ M } = 1.959 \\\\

Therefore,

t =\frac{1.959}{0.54} = 3.63\ seconds

  • Hence, the it would take 3.63 seconds for the concentration of NO_{2} to decrease from 0.62 M to 0.28 M if the reaction is second order.

To learn more about second order reaction visit:

brainly.com/question/17217385

#SPJ4

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Answer:

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Explanation:

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3 years ago
Arrange the following in order of increasing bond strength of the carbon oxygen bond:
Brilliant_brown [7]

Answer:

The correct option is: Carbonate ion < Carbon dioxide < Carbon monoxide

Explanation:

Bond energy is defined as the average energy needed to break a chemical covalent bond and signifies the strength of chemical covalent bond.

The bond strength of a covalent bond depends upon the <u>bond length and the bond order.</u>

Carbon monoxide molecule (CO) has two covalent bond and one dative bond. Bond order 2.6

Carbon dioxide (CO₂) has two carbon-oxygen (C-O) double bonds of equal length. Bond order 2.0

Carbonate ion (CO₃²⁻) has three C-O partial double bonds. Bond order 1.5

Also, the bond length is <u>inversely proportional to the bond order and bond strength.</u>

Therefore, <u>order of C-O bond length:</u> Carbon monoxide<Carbon dioxide<Carbonate ion

<u>Order of C-O bond order</u>: Carbonate ion<Carbon dioxide<Carbon monoxide

<u>Order of C-O bond strength or energy</u><u>: Carbonate ion<Carbon dioxide<Carbon monoxide</u>

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3 years ago
Which reagent is the limiting reactant when 0.700 mol al(oh)3 and 0.700 mol h2so4 are allowed to react?
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Which of the following was NOT suggested by Rutherford’s gold foil experiment?
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Calculate the heat energy required to melt 4kg of ice when the specific latent heat of fusion of water is 334,000 J/kg.
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Taking into account the definition of calorimetry and latent heat, the heat energy required to melt 4 kg of ice when the specific latent heat of fusion of water is 334,000 \frac{J}{kg} is 1,336 kJ.

<h3>Calorimetry</h3>

Calorimetry is the measurement and calculation of the amounts of heat exchanged by a body or a system.

<h3>Latent heat</h3>

Latent heat is defined as the energy required by a quantity of substance to change state.

When this change consists of changing from a solid to a liquid phase, it is called heat of fusion and when the change occurs from a liquid to a gaseous state, it is called heat of vaporization.

The heat Q that is necessary to provide for a mass m of a certain substance to change phase is equal to

Q = m×L

where L is called the latent heat of the substance and depends on the type of phase change.

<h3>Heat energy required to melt ice</h3>

In this case, you know:

  • m= 4 kg
  • L= specific latent heat of fusion of water= 334,000 \frac{J}{kg}

Replacing in the expression for latent heat:

Q = 4 kg× 334,000 \frac{J}{kg}

Solving:

<u><em>Q= 1,336,000 J= 1,336 kJ </em></u>(being 1,000 J= 1 kJ)

Finally, the correct answer is the first option: the heat energy required to melt 4 kg of ice when the specific latent heat of fusion of water is 334,000 \frac{J}{kg} is 1,336 kJ.

Learn more about calorimetry:

<u>brainly.com/question/14057615?referrer=searchResults</u>

<u>brainly.com/question/24988785?referrer=searchResults</u>

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<u>brainly.com/question/14309811?referrer=searchResults</u>

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