<u>Answer:</u> The freezing point of solution is 2.6°C
<u>Explanation:</u>
To calculate the depression in freezing point, we use the equation:

Or,

where,
= 
Freezing point of pure solution = 5.5°C
i = Vant hoff factor = 1 (For non-electrolytes)
= molal freezing point depression constant = 5.12 K/m = 5.12 °C/m
= Given mass of solute (anthracene) = 7.99 g
= Molar mass of solute (anthracene) = 178.23 g/mol
= Mass of solvent (benzene) = 79 g
Putting values in above equation, we get:

Hence, the freezing point of solution is 2.6°C
Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
So we know the number of moles of each compound. If we need to know the concentration we must know the number of moles that the compounds react with...