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laila [671]
3 years ago
10

A chemist titrates 160.0mL of a 0.3403M aniline C6H5NH2 solution with 0.0501M HNO3 solution at 25°C . Calculate the pH at equiva

lence. The pKb of aniline is 4.87 . Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of HNO3 solution added.
Chemistry
1 answer:
maxonik [38]3 years ago
4 0

Answer : The pH of the solution is, 5.24

Explanation :

First we have to calculate the volume of HNO_3

Formula used :

M_1V_1=M_2V_2

where,

M_1\text{ and }V_1 are the initial molarity and volume of C_6H_5NH_2.

M_2\text{ and }V_2 are the final molarity and volume of HNO_3.

We are given:

M_1=0.3403M\\V_1=160.0mL\\M_2=0.0501M\\V_2=?

Putting values in above equation, we get:

0.3403M\times 160.0mL=0.0501M\times V_2\\\\V_2=1086.79mL

Now we have to calculate the total volume of solution.

Total volume of solution = Volume of C_6H_5NH_2 +  Volume of HNO_3

Total volume of solution = 160.0 mL + 1086.79 mL

Total volume of solution = 1246.79 mL

Now we have to calculate the Concentration of salt.

\text{Concentration of salt}=\frac{0.3403M}{1246.79mL}\times 160.0mL=0.0437M

Now we have to calculate the pH of the solution.

At equivalence point,

pOH=\frac{1}{2}[pK_w+pK_b+\log C]

pOH=\frac{1}{2}[14+4.87+\log (0.0437)]

pOH=8.76

pH+pOH=14\\\\pH=14-pOH\\\\pH=14-8.76\\\\pH=5.24

Thus, the pH of the solution is, 5.24

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Positive Deviation from Raoult's Law occurs when the vapour pressure of component is greater than what is expected in Raoult's L
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Answer:

All of the above.

Explanation:

In positive deviation from Raoult's  Law occur when the vapour pressure of components is greater than what is expected value in Raoult's law.

When a solution is non ideal then it shows positive or negative deviation.

Let two solutions A and B to form non- ideal solutions.let the vapour pressure  of component A is P_A and vapour pressure of component B is P_B.

P^0_A= Vapour pressure of component A in pure form

P^0_B= Vapour pressure of component B in pure form

x_A=Mole fraction of component A

x_B==Mole fraction of component B

The interaction between A- B is less than the interaction A- A and B-B interaction.Therefore, the escaping tendency of liquid molecules in mixture is greater than the escaping tendency in pure form.Hence, the vapour pressure of a mixture is greater than the initial value of vapour pressure.

P_A >P^0_A\cdot x_A,P_B>P^0_B\cdot x_B

Therefore, P_A+P_B >P^0_A\cdot x_A+P^0_B \cdot x_B

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Explanation:

The given data is as follows.

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                             = 0.1 \frac{mol dm^{3}}{dm^{3}} \frac{10^{3}}{dm^{3}} \times \frac{6.022 \times 10^{23}}{1 mol} ions

                             = 6.022 \times 10^{25} ions/m^{3}

               T = 30^{o}C = (30 + 273) K = 303 K

Formula for electric double layer thickness (\lambda_{D}) is as follows.

            \lambda_{D} = \frac{1}{k} = \sqrt \frac{\varepsilon \varepsilon_{o} K_{g}T}{2 n^{o} z^{2} \varepsilon^{2}}

where, n^{o} = concentration = 6.022 \times 10^{25} ions/m^{3}

Hence, putting the given values into the above equation as follows.

                 \lambda_{D} = \sqrt \frac{\varepsilon \varepsilon_{o} K_{g}T}{2 n^{o} z^{2} \varepsilon^{2}}                    

                          = \sqrt \frac{78 \times 8.854 \times 10^{-12} c^{2}/Jm \times 1.38 \times 10^{-23}J/K \times 303 K}{2 \times 6.022 \times 10^{25} ions/m^{3} \times (1)^{2} \times (1.6 \times 10^{-19}C)^{2}}  

                         = 9.669 \times 10^{-10} m

or,                     = 9.7 A^{o}

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Also, it is known that \lambda_{D} = \sqrt \frac{1}{n^{o}}

Hence, we can conclude that addition of 0.1 mol/dm^{3} of KCl in 0.1 mol/dm^{3} of NaBr "\lambda_{D}" will decrease but not significantly.

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A catalytic converter changes nitrogen dioxide to nitrogen gas and oxygen gas is a chemical change.

Explanation:

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In this case, since physical changes do not modify the molecular composition and structure of the material undergoing it whereas the chemical change does, for catalytic converters we should know they promote chemical reaction in which the composition is changed; for instance, for the given example, the following chemical reaction is the evidence:

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Best regards.

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