1answer.
Ask question
Login Signup
Ask question
All categories
  • English
  • Mathematics
  • Social Studies
  • Business
  • History
  • Health
  • Geography
  • Biology
  • Physics
  • Chemistry
  • Computers and Technology
  • Arts
  • World Languages
  • Spanish
  • French
  • German
  • Advanced Placement (AP)
  • SAT
  • Medicine
  • Law
  • Engineering
umka21 [38]
3 years ago
9

Find an expression for the change in entropy when two blocks of the same substance of equal mass, one at the temperature Th and

the other at Tc, are brought into contact and allowed to reach equilibrium. Evaluate the change for the two blocks of copper, each of mass 500 grams with Cpcm= 24.4 J KT-1 mol-1, taking Th = 500 K and Tc = 250 K.
Chemistry
1 answer:
Gre4nikov [31]3 years ago
8 0

Explanation:

Relation between entropy change and specific heat is as follows.

            \Delta S = C_{p} log (\frac{T_{2}}{T_{1}})

The given data is as follows.

     mass = 500 g,         C_{p} = 24.4 J/mol K

     T_{h} = 500 K,          T_{c} = 250 K               

   Mass number of copper = 63.54 g /mol

Number of moles = \frac{mass}{/text{\molar mass}}

                                 = \frac{500}{63.54}

                                 = 7.86 moles

Now, equating the entropy change for both the substances as follows.

     7.86 \times 24.4 \times [T_{f} - 250] = 7.86 \times 24.4 \times [500 -T_{f}]

       T_{f} - 250 = 500 - T_{f}

          2T_{f} = 750

So,       T_{f} = 375^{o}C

  • For the metal block A,  change in entropy is as follows.

         \Delta S = C_{p} log (\frac{T_{2}}{T_{1}})

              = 24.4 log [\frac{375}{500}]

              = -3.04 J/ K mol

  • For the block B,  change in entropy is as follows.

         \Delta S = C_{p} log (\frac{T_{2}}{T_{1}})

                  = 24.4 log [\frac{375}{250}]

                  = 4.296  J/Kmol

And, total entropy change will be as follows.

                       = 4.296 + (-3.04)

                      = 1.256 J/Kmol

Thus, we can conclude that change in entropy of block A is -3.04 J/ K mol  and change in entropy of block B is 4.296  J/Kmol.

You might be interested in
How did u get 0.19278 moles of Sb?
Bingel [31]

Answer:

The mole is represented by Avogadro’s number, which is 6.022×1023 atoms or molecules per mol.

LEARNING OBJECTIVES

Define and memorize Avogadro’s number

KEY TAKEAWAYS

Key Points

The mole allows scientists to calculate the number of elementary entities (usually atoms or molecules ) in a certain mass of a given substance.

Avogadro’s number is an absolute number: there are 6.022×1023 elementary entities in 1 mole. This can also be written as 6.022×1023 mol-1.

The mass of one mole of a substance is equal to that substance’s molecular weight. For example, the mean molecular weight of water is 18.015 atomic mass units (amu), so one mole of water weight 18.015 grams.

Key Terms

mole: The amount of substance of a system that contains as many elementary entities as there are atoms in 12 g of carbon-12.

The chemical changes observed in any reaction involve the rearrangement of billions of atoms. It is impractical to try to count or visualize all these atoms, but scientists need some way to refer to the entire quantity. They also need a way to compare these numbers and relate them to the weights of the substances, which they can measure and observe. The solution is the concept of the mole, which is very important in quantitative chemistry.

Avogadro’s Number

image

Amedeo Avogadro: Amedeo Avogadro is credited with the idea that the number of entities (usually atoms or molecules) in a substance is proportional to its physical mass.

Amadeo Avogadro first proposed that the volume of a gas at a given pressure and temperature is proportional to the number of atoms or molecules, regardless of the type of gas. Although he did not determine the exact proportion, he is credited for the idea.

Avogadro’s number is a proportion that relates molar mass on an atomic scale to physical mass on a human scale. Avogadro’s number is defined as the number of elementary particles (molecules, atoms, compounds, etc.) per mole of a substance. It is equal to 6.022×1023 mol-1 and is expressed as the symbol NA.

Avogadro’s number is a similar concept to that of a dozen or a gross. A dozen molecules is 12 molecules. A gross of molecules is 144 molecules. Avogadro’s number is 6.022×1023 molecules. With Avogadro’s number, scientists can discuss and compare very large numbers, which is useful because substances in everyday quantities contain very large numbers of atoms and molecules.

The Mole

The mole (abbreviated mol) is the SI measure of quantity of a “chemical entity,” such as atoms, electrons, or protons. It is defined as the amount of a substance that contains as many particles as there are atoms in 12 grams of pure carbon-12. So, 1 mol contains 6.022×1023 elementary entities of the substance.

Chemical Computations with Avogadro’s Number and the Mole

Avogadro’s number is fundamental to understanding both the makeup of molecules and their interactions and combinations. For example, since one atom of oxygen will combine with two atoms of hydrogen to create one molecule of water (H2O), one mole of oxygen (6.022×1023 of O atoms) will combine with two moles of hydrogen (2 × 6.022×1023 of H atoms) to make one mole of H2O.

Another property of Avogadro’s number is that the mass of one mole of a substance is equal to that substance’s molecular weight. For example, the mean molecular weight of water is 18.015 atomic mass units (amu), so one mole of water weight 18.015 grams. This property simplifies many chemical computations.

If you have 1.25 grams of a molecule with molecular weight of 134.1 g/mol, how many moles of that molecule do you have?

1.25

g

×

1

mole

134.1

g

=

0.0093

moles

7 0
3 years ago
Bam what!!!!!!!!!!!!!!!!!!!!!!!!!!1
elixir [45]

Answer:

Oh yea hey

Explanation:

This is from Liv and Maddie

4 0
3 years ago
Read 2 more answers
Why do i need to make a hypothesis
lana [24]

Answer:

A hypothesis is a statement that can be tested by scientific research. If you want to test a relationship between two or more things, you need to write hypotheses before you start your experiment or data collection.

Explanation:

7 0
3 years ago
Read 2 more answers
When elemental sodium reacts with water, sodium hydroxide and hydrogen will form. What mass of sodium (in grams) must be reacted
tangare [24]

Answer:

0.703g Na must reacted

Explanation:

The reaction of Sodium, Na, With water, H₂O is:

2Na(s) + 2H₂O(l) → 2NaOH(aq) + H₂(g)

<em>Where 2 moles of sodium reacts with an excess of water to produce 1 mole of hydrogen</em>

<em />

To solve this question we have to use PV = nTR to solve the moles of the gas. With the moles of hydrogen we can find the moles of sodium that reacted and its mass:

<em>Moles H₂:</em>

PV = nRT

PV /RT = n

<em>Where P is pressure = 1.15atm</em>

<em>V is volume in liters = 0.325L</em>

<em>R is gas constant = 0.082atmL/molK</em>

<em>T is absolute temperature = 25°C + 273 = 298.0K</em>

<em />

1.15atm*0.325L / 0.082atmL/molK*298.0K = n

0.0153 moles of hydrogen are produced

<em>Moles Na:</em>

0.0153 moles H₂ * (2moles Na / 1mol H₂) = 0.0306 moles Na

<em>Mass Na -Molar mass: 22.99g/mol-:</em>

0.0306 moles Na * (22.99g / mol) =

<h3>0.703g Na must reacted</h3>
8 0
3 years ago
Which solution will have the highest ph? the ka of hclo is 3.8 × 10−8.
Ilya [14]
The one with the highest pH would be a solution with 100 mL of water and also 20 mL of 0.1 M NaOH is added. Solutions without buffers would have the highest pH since the resistance to change is very low. Hope this answers the question.
3 0
3 years ago
Other questions:
  • กระบวนการหายใจเกิดขึ้นกับเซลล์ทุกเซลล์หรือไม่ อย่างไร
    15·1 answer
  • All the subatomic particles participate in chemical reactions. <br> a. True <br> b. False
    7·1 answer
  • Treating one coworker better than others is called vertical relationship. favoritism. harmony. socializing.
    9·1 answer
  • Which statement describes one acid-base theory?
    9·1 answer
  • All of the following show a periodic pattern except
    10·1 answer
  • Which state of matter has neutral particles that bounce off one another as they collide?
    11·2 answers
  • What are the factors of diffusion?
    11·2 answers
  • Which unit of measurement should be used for the vertical axis? A. millimeters B. centimeters C. kilometers D. decimeters
    13·1 answer
  • Plants make food (sugar) using sunlight, carbon dioxide from the air, and
    11·1 answer
  • How many carbon atoms are in my sample
    8·1 answer
Add answer
Login
Not registered? Fast signup
Signup
Login Signup
Ask question!