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enot [183]
3 years ago
9

Which types of electron orbitals will have higher energy than a 4d orbital?

Chemistry
1 answer:
alexdok [17]3 years ago
8 0

Answer:

D) 4f

Explanation:

To determine which electron orbital that will have higher energy than a 4d orbital, we write the electron configuration starting with s-orbital.

1s

2s         2p

3s         3p          3d       3f

4s         4p          4d       4f

5s         5p           5d       5f

6s         6p          6d       6f

7s         7p           7d       7f

In ascending order, 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 3f, <u>4d</u><em>,</em> 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p, 6f, 7d, 7f.

From the electronic configuration formula above, the electron orbitals that have higher energy than a 4d orbital are 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p, 6f, 7d, 7f.

Therefore, 4f is the correct answer.

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What volume is used to calculate the volume of a solid object ​
Degger [83]

Answer:

cubic measurements

Explanation:

i.e. cubic meter or cubic centimeter

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What is oxidized in a galvanic cell with aluminum and gold electrodes ?
k0ka [10]

Answer:

Aluminum metal

Explanation:

In order to properly answer this or a similar question, we need to know some basic rules about galvanic cells and standard reduction potentials.

First of all, your strategy would be to find a trusted source or the table of standard reduction potentials. You would then need to find the half-equations for aluminum and gold reduction:

Al^{3+}+3e^-\rightarrow Al; E^o=-1.66 V

Au^{3+}+3e^-\rightarrow Au; E^o=1.50 V

Since we have a galvanic cell, the overall reaction is spontaneous. A spontaneous reaction indicates that the overall cell potential should be positive.

Since one half-equation should be an oxidation reaction (oxidation is loss of electrons) and one should be a reduction reaction (reduction is gain of electrons), one of these should be reversed.

Thinking simply, if the overall cell potential would be obtained by adding the two potentials, in order to acquite a positive number in the sum of potentials, we may only reverse the half-equation of aluminum (this would change the sign of E to positive):Al\rightarrow Al^{3+}+3e^-; E^o=1.66 V\\Au^{3+}+3e^-\rightarrow Au; E^o=1.50 V

Notice that the overall cell potential upon summing is:

E_{cell}=1.66 V + 1.50 V=3.16 V

Meaning we obey the law of galvanic cells.

Since oxidation is loss of electrons, notice that the loss of electrons takes place in the half-equation of aluminum: solid aluminum electrode loses 3 electrons to become aluminum cation.

6 0
3 years ago
One mole of a monatomic ideal gas is subjected to the following sequence of steps: a. Starting at 300 K and 10 atm, the gas expa
Verdich [7]

Answer:

a) Q = 0; W = 0; ΔU = 0; ΔH = 0; ΔS = 0.09 atm.L/K

b) Q = 1250 J; W = 0; ΔU = 1250 J; ΔH = 1250 J; ΔS = -0.0235 atm.L/K

c) Q = 3653.545 J; W = - 3653.545 J; ΔU = 0; ΔH = 0; ΔS = - 3653.545 J

d) Q = - 2080 J; W = 830 J; ΔU = - 1250 J; ΔH = - 2080 J; ΔS = - 5.984 J/K

Explanation:

a) If there is a vacuum, the work is zero, as it is a free expansion, the volume increases, the pressure decreases, the temperature is constant and the internal energy is constant.

∴ n = 1 mole

∴ PV = RTn....ideal gas

∴ P1 = 10 atm

∴ R = 0.082 atm.L/K.mol

∴ T = 300 K = T2

∴ V2 = 3*V1

⇒ W = 0.....expands freely into vacuum

⇒ ΔU = Q = 0....first law

⇒ ΔS = -  nR Ln(P2/P1).....ideal gas

∴ V1*P1/T1 = V2*P2/T2

∴ T1 = T2 = 300 K

⇒ P2 = V1*P1 / V2 = V1*P1 / 3V1 = 10 atm/3 = 3.33 atm

⇒ ΔS = - (1mol)*(0.082 atm.L/K.mol) Ln ( 3.33/10)

⇒ ΔS = 0.09 atm.L/K

∴ ΔH = ΔU + (P2V2 - P1V1) = 0 + 0 = 0

b) heated reversibly at constant volume:

⇒ W = 0 ...at constant volume

∴ T2 = 400 K; T1 = 300 K

∴ V1 = V2

⇒ Q = ΔU = CvΔT....first law

∴ Cv = 12.5 J/K.mol.....monoatomic ideal gas

∴ ΔT = 400 - 300 = 100 K

⇒ Q = ΔU = 12.5 J/mol.K * 100K = 1250 J/mol * 1 mol = 1250 J

∴ ΔH = ΔU + PΔV = ΔU + 0 = 1250 J

∴ ΔS = - nR Ln (P2/P1)

∴ P2/T2 = P1/T1...constant volume

∴ P1 = 3.33 atm

⇒ P2 = P1*T2 / T1 = (3.33 atm)*(400K) / (300K) = 4.44 atm

⇒ ΔS = - (1mol)*(0.082atm.L/K.mol) Ln (4.44/3.33)

⇒ ΔS = - 0.0235 atm.L/K

c) reversibly expanded at constant temperature:

∴ T1 = T2 = 400K

∴ V2 = 3*V1

∴ ΔU = 0...constant temperature

⇒ Q = - W....fisrt law

∴ W = - ∫ PdV..... reversibly expansion

∴ P = nRT/V... ideal gas

⇒ W = - nRT ∫ dV/V

⇒ W = - nRT Ln (V2/V1)

⇒ W = - (1mol)*(8.314 J/K.mol) Ln (3)

⇒ W = - 9.134 J/K *400K = - 3653.545 J

⇒ Q = - W = 3653.545 J

⇒ ΔH = ΔU + P1V1 - P2V2 = 0 + nRT1 - nRT2 = 0 + 0 = 0

∴ ΔS = - nR Ln(P2/P1)

∴ P1 = 4.44 atm

⇒ P2 = V1*P1*T2/ V2*T1 = V1*(4.44atm)*(400K) / (3.V1)*(400K)

⇒ P2 = 4.44atm/3 = 1.48 atm

⇒ ΔS = - (1mol)*(8.314 J/mol.K) Ln (1.48/4.44)

⇒ ΔS = -9.134J/K * 400K = - 3653.545 J

d) reversibly cooled at constant pressure:

∴ T2 = 300 K;  T1 = 400 K

∴ P2 = P1

⇒ Q = ΔH = CpΔT

∴ Cp = 20.8 J/K.mol

∴ ΔT = 300 - 400 = - 100 K

⇒ Q = ΔH = 20.8 J/mol.K * ( -100K) = - 2080 J/mol * 1mol = - 2080 J

⇒ ΔU = nCvΔT = (1mol)*(12.5 J/mol.K)*( - 100K) = -1250 J

⇒ W = ΔU - Q = ΔU - ΔH = -1250 J - ( - 2080 J ) = 830 J

∴ ΔS = ∫ δQ/T = ∫ nCpdT/T

⇒ ΔS = nCp Ln (T2/T1)

⇒ ΔS = (1mol)*(20.8 J/mol.K) Ln (300/400) = - 5.984 J/K

7 0
3 years ago
n an experiment, 39.26 mL of 0.1062 M NaOH solution was required to titrate 37.54 mL of \ v unknown acetic acid solution to a ph
olasank [31]

Answer:

Molarity: 0.111M

% (w/w): 0.666

Explanation:

The reaction of NaOH with acetic acid (CH₃COOH) is:

NaOH + CH₃COOH → CH₃COO⁻Na⁺ + H₂O

<em>where 1 mole of NaOH reacts per mole of acetic acid producing 1 mole of water and 1 mole of sodium acetate.</em>

As 39.26mL ≡ 0.03926L of 0.1062M are required to titrate the solution of acetic acid. Moles are:

0.03926L × (0.1062mol / L) = 4.169x10⁻³ moles of NaOH. As 1 mole of NaOH reacts per mole of acetic acid:

4.169x10⁻³ moles of CH₃COOH.

Molarity is defined as ratio between moles of substance and volume of solution in liters. Thus, molarity of acetic acid solution is:

4.169x10⁻³ moles of CH₃COOH / 0.03754L = <em>0.111M</em>

<em></em>

As molar mass of acetic acid is 60g/mol, 4.169x10⁻³ moles weights:

4.169x10⁻³ moles × (60g / mol) = <em>0.2501 g of acetic acid</em>

Now, assuming density of solution as 1.00g/mL, 37.54mL weights <em>37.54g</em>.

Thus, percent by weight is:

0.2501g CH₃COOH / 37.54g × 100 = <em>0.666% (w/w)</em>

8 0
3 years ago
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