Answer:
Sulfur hexafluoride, also known as sulfur(VI) fluoride, is a chemical compound. Its chemical formula is SF6. It contains sulfur in its +6 oxidation state.
Answer : The ratio of
to
is, 
Solution : Given,

= 0.21 atm
The given equilibrium reaction is,

The expression of
will be,

Now put all the given values in this expression, we get:



Therefore, the ratio of
to
is, 
The final gas pressure : 175.53 atm
<h3>Further explanation</h3>
Maybe the complete question is like this :
A ridged steel tank filled with 62.7 l of nitrogen gas at 85.0 atm and 19 °C is heated to 330 °C while the volume remains constant. what is the final gas pressure?
The volume remains constant⇒Gay Lussac's Law
<em>When the volume is not changed, the gas pressure in the tube is proportional to its absolute temperature </em>

P₁=85 atm
T₁=19+273=292 K
T₂=330+273=603 K

I think it is d it is definitely not a or b