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ExtremeBDS [4]
3 years ago
6

Define the following symbols that are encountered in rate equations: [A]0, t1/2 [A]t, k.

Chemistry
1 answer:
dezoksy [38]3 years ago
5 0
[A]0= Initial concentration
t1/2= half life
[A]= final concentration
k= rate constant
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Consider the following reaction at constant P. Use the information here to determine the value of ΔSsurr at 355 K. Predict wheth
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Answer:

\Delta S_{surr} = + 0.32113\: kJ/K

Explanation:

Given: Entropy of surrounding: ΔSsurr = ?

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Pressure: P = constant

As we know, ΔH = -114 kJ ⇒ negative

Therefore, the given reaction is an exothermic reaction

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\Delta S_{surr} = \frac{-\Delta H}{T}

\therefore \Delta S_{surr} = -\left (\frac{-114 kJ}{355 K}  \right ) = + 0.32113\: kJ/K > 0

<u><em>In the given reaction:</em></u>

2NO(g) + O₂(g) → 2NO₂(g)

As, the number of moles of gaseous products is less than the number of moles of gaseous reactants.

\therefore \Delta S_{system} <  0

As we know, <em>for a spontaneous process, that the total entropy should be positive.</em>

\Delta S_{total} = \Delta S_{surr} + \Delta S_{system} > 0  

<u>Therefore, at the given temperature,</u>

  • if \Delta S_{surr} > \Delta S_{system} \Rightarrow \Delta S_{total} > 0 then the given reaction is spontaneous
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Have a great summer :)

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You would find the atomic weight of phosphorus and multiply that 2.3 and get 71.23.
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