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mr Goodwill [35]
3 years ago
12

The black "smoke" that flows out of deep ocean hydrothermal vents is made of insoluble metal sulfides suspended in seawater. Of

the following cations that are present in the water flowing up through these vents, which ones could contribute to the formation of the black smoke?
Pb2+
Mn2+
Mg2+
Cu2+
Na+
Li+
Zn2+
Fe2+
Ca2+
Chemistry
1 answer:
GREYUIT [131]3 years ago
8 0
The solubility rules usually go on to say that group IIA sulfides are soluble, but actually group IIA sulfides react with water to make H2S and the group IIA metal hydroxide. 
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A 1.00 g sample of octane (C8H18) is burned in a bomb calorimeter with a heat capacity of 837J∘C that holds 1200. g of water at
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Answer:

The heat of combustion for 1.00 mol of octane is  -5485.7 kJ/mol

Explanation:

<u>Step 1:</u> Data given

Mass of octane = 1.00 grams

Heat capacity of calorimeter = 837 J/°C

Mass of water = 1200 grams

Temperature of water = 25.0°C

Final temperature : 33.2 °C

<u> Step 2:</u> Calculate heat absorbed by the calorimeter

q = c*ΔT

⇒ with c = the heat capacity of the calorimeter = 837 J/°C

⇒ with ΔT = The change of temperature = T2 - T1 = 33.2 - 25.0 : 8.2 °C

q = 837 * 8.2 = 6863.4 J

<u>Step 3:</u> Calculate heat absorbed by the water

q = m*c*ΔT

⇒ m = the mass of the water = 1200 grams

⇒ c = the specific heat of water = 4.184 J/g°C

⇒ ΔT = The change in temperature = T2 - T1 = 33.2 - 25  = 8.2 °C

q = 1200 * 4.184 * 8.2 =  41170.56 J

<u>Step 4</u>: Calculate the total heat

qcalorimeter + qwater = 6863.4 + 41170. 56 = 48033.96 J  = 48 kJ

Since this is an exothermic reaction, there is heat released. q is positive but ΔH is negative.

<u>Step 5</u>: Calculate moles of octane

Moles octane = 1.00 gram / 114.23 g/mol

Moles octane = 0.00875 moles

<u>Step 6:</u> Calculate heat combustion for 1.00 mol of octane

ΔH = -48 kJ / 0.00875 moles

ΔH = -5485.7 kJ/mol

The heat of combustion for 1.00 mol of octane is  -5485.7 kJ/mol

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