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ArbitrLikvidat [17]
3 years ago
15

The change in the standard Gibbs free energy (ΔGº) for the dissociation of nitrous acid (HNO2) at 298 K is 19.09 kJ. If the pH o

f the solution after equilibrium is reached is 1.30 and the NO2 – concentration at equilibrium is 0.00060 M. What is the equilibrium concentration of HNO2? Hint: Use pH to determine the equilibrium concentration of H+ .
Chemistry
1 answer:
Fynjy0 [20]3 years ago
4 0
The change in the standard Gibbs free energy (ΔGº) for the dissociation of nitrous acid (HNO2) at 298 K is 19.09 kJ. If the pH of the solution after equilibrium is reached is 1.30 and the NO2 – concentration at equilibrium is 0.00060 M. What is the equilibrium concentration of HNO2? Hint: Use pH to determine the equilibrium concentration of H+ .
HNO2(aq) H + (aq) + NO2 – (aq)
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Explanation:

Since, it is shown that the reaction has been reversed. Therefore, value of K_{c} will become \frac{1}{K_{c}}.

Hence, new K_{c'} = \frac{1}{K_{c}}

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                                      = 20

Also, the number of moles of each reactant has been halved. So, K_{c''} for the reaction MgO(s) + \frac{1}{2}Cl2(g) → MgCl_{2}(s) + \frac{1}{2} O2(g) will also get halved.

Therefore,     K_{c''}  = K_{c'} = (20)^{0.5}

                               = 4.47

As the value of \Delta H is given as +39.0 kJ. So, it means that the reaction is endothermic in nature. So, energy of reactants will be more than the products. Hence, according to Le Chatelier's principle reaction will move in the forward direction.

As a result, K_{c} will also increase with increase in temperature.

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Question 11 (1 point)
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  • If a system at equilibrium is disturbed, by changing the concentration of one of the substances all the concentrations will change until a new equilibrium point is reached.
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