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ArbitrLikvidat [17]
4 years ago
15

The change in the standard Gibbs free energy (ΔGº) for the dissociation of nitrous acid (HNO2) at 298 K is 19.09 kJ. If the pH o

f the solution after equilibrium is reached is 1.30 and the NO2 – concentration at equilibrium is 0.00060 M. What is the equilibrium concentration of HNO2? Hint: Use pH to determine the equilibrium concentration of H+ .
Chemistry
1 answer:
Fynjy0 [20]4 years ago
4 0
The change in the standard Gibbs free energy (ΔGº) for the dissociation of nitrous acid (HNO2) at 298 K is 19.09 kJ. If the pH of the solution after equilibrium is reached is 1.30 and the NO2 – concentration at equilibrium is 0.00060 M. What is the equilibrium concentration of HNO2? Hint: Use pH to determine the equilibrium concentration of H+ .
HNO2(aq) H + (aq) + NO2 – (aq)
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n(\text{C}_3\text{H}_7\text{OH}) = N(\text{C}_3\text{H}_7\text{OH}) / N_A\\ \phantom{n(\text{C}_3\text{H}_7\text{OH})} = 5.2 \times 10^{21} / (6.02 \times 10^{23})\\ \phantom{n(\text{C}_3\text{H}_7\text{OH})} = 8.6 \times 10^{-3} \; \text{mol}

where N_A = 6.02 \times 10^{23}\; \text{mol}^{-1} the Avogadro's constant that relates the number of particles to their number, in the unit moles \text{mol}.

The molar mass of propanol- mass per mole propanol- can be directly deduced from its molecular formula with reference to a modern periodic table.

M(\text{C}_3\text{H}_7\text{OH}) = \underbrace{3 \times 12.01}_{\text{carbon}} + \underbrace{8 \times 1.008}_{\text{hydrogen}} + \underbrace{1\times 16.00}_{\text{oxygen}} = 60.09 \; \text{g} \cdot \text{mol}^{-1}

8.6 \times 10^{-3} \; \text{mol} of propanol molecules would thus have a mass of 8.6 \times 10^{-3} \; \text{mol} \times 60.09 \; \text{g} \cdot \text{mol}^{-1} = 0.52 \; \text{g}

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The structure of n‑methyl‑2‑pyrrolidone when it is heated with aqueous acid. product is given below

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