the law of thermodyanamic is the restatement of the law of conservation of energy
Answer : The enthalpy of the given reaction will be, -1048.6 kJ
Explanation :
According to Hess’s law of constant heat summation, the heat absorbed or evolved in a given chemical equation is the same whether the process occurs in one step or several steps.
The main reaction is:

The intermediate balanced chemical reactions are:
(1)

(2)

(3)

(4)

(5)

Now reversing reaction 2, multiplying reaction 3 by 4, reversing reaction 1 and multiplying by 2, reversing reaction 5 and multiplying by 2 and then adding all the equations, we get :
(1)

(2)

(3)

(4)

(5)

The expression for enthalpy of main reaction will be:



Therefore, the enthalpy of the given reaction will be, -1048.6 kJ
Answer:
Explanation has been given below.
Explanation:
- Chloroform has three polar C-Cl bonds. Methylene chloride has two polar C-Cl bonds. So it is expected that chloroform should be more polar and posses higher dipole moment than methylene chloride.
- Two factors are liable for the opposite trend observed in dipole moments of methylene chloride and chloroform.
- First one is the number of hyperconjugative hydrogen atoms present in a molecule. Hyperconjugation occurs with vacant d-orbital of Cl atom. Hyperconjugation amplifies charge separation in a molecule resulting higher dipole moment.
- Methylene chloride has two hyperconjugative hydrogen atoms and chloroform has one hyperconjugative hydrogen atom.Therefore methylene chloride should have higher charge separation as compared to chloroform.
- Second one is induction of opposite polarity in a C-Cl bond by another C-Cl bond in a molecule. Higher the opposite induction of polarity, lower the charge separation in a molecule and hence lower the dipole moment of a molecule.
- Chloroform has three C-Cl bonds and methylene chloride has two C-Cl bonds. Therefore opposite induction is higher for chloroform resulting it's lower dipole moment.
Hot liquid rock comes in contact with Earth´s cold crust
Answer:
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