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Elza [17]
3 years ago
9

When chemical bond are broken, energy is

Chemistry
1 answer:
Zarrin [17]3 years ago
8 0

Energy is absorbed to break bonds, and released when bonds are formed.

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The protein lysozyme unfolds at a transition temperature of 75.5°C, and the standard enthalpy of transition is 509 kJ mol-1. Cal
spin [16.1K]

Answer:

0.4774 KJ/K.mol

Explanation:

We are told that the transition at 25.0°C occurs in three steps. Steps i, ii and iii.

Thus;

the entropy of unfolding of lysozyme = ΔS_i + ΔS_ii + ΔS_iii

Now,

C_p,m(unfolded protein) = C_p,m(folded protein) + 6.28 kJ/K.mol

Now, for the first process, ΔS_i is given as;

ΔS_i = C_p,m × In(T2/T1)

We are given;

T1 = 25°C = 25 + 273.15K = 298.15 K

T2 = 75.5°C = 75.5 + 273.15 K=348.65 K

Thus;

ΔS_i = C_p,m × In(348.65/298.15)

Now, for the third process, ΔS_iii is given as;

ΔS_iii = (C_p,m + 6.28 kJ/K.mol) × In(T1/T2)

Thus;

ΔS_iii = (C_p,m + 6.28 kJ/K.mol) × In(298.15/348.65)

Now, we don't know C_pm. So, we have to find a way to eliminate it. We will do it by rewriting In(298.15/348.65) in such a way that when ΔS_iii is added to ΔS_i, C_p,m will cancel out. Thus;

In(298.15/348.65) can also be written as;

In(348.65/298.15)^(-1) or

- In(348.65/298.15)

Thus;

ΔS_iii = - [(C_p,m + 6.28 kJ/K.mol) × In(298.15/348.65)]

Now, let's add ΔS_iii to ΔS_i to get;

ΔS_i + ΔS_iii = [C_p,m × In(348.65/298.15)] + [(-C_p,m - 6.28 kJ/K.mol) × In(348.65/298.15)]

ΔS_i + ΔS_iii = [C_p,m × In(348.65/298.15)] - [C_p,m × In(348.65/298.15)] - [6.28In(348.65/298.15)]

First 2 terms will cancel out to give;

ΔS_i + ΔS_iii = -6.28In(348.65/298.15)

ΔS_i + ΔS_iii = -0.9826 KJ/K.mol

Now,for process ii;

ΔS_ii = standard enthalpy of transition/Transition Temperature

Thus;

ΔS_ii = (509 KJ/K.mol)/348.65

ΔS_ii = 1.46 KJ/K.mol

Thus;

the entropy of unfolding of lysozyme = ΔS_i + ΔS_ii + ΔS_iii = -0.9826 + 1.46 = 0.4774 KJ/K.mol

5 0
3 years ago
Compare 1 mole of H2, 1 mole of O2, and 1 mole of F2. (a) Which has the largest number of molecules? Explain why. (b) Which has
AURORKA [14]

<u>a) Answer: </u>

<em>Number of molecules in 1 mole</em>

<u>Explanation:</u>

a) Whether we take any of the substance among all three of the given substances they will have the same number of molecules in 1 mole of the substance is considered and the value for this will be 6.023 x 10^23

<u>b)  Answer: </u>

<em>In the given question </em><em>mass of the substance</em><em> which is </em><em>greatest</em><em> is asked for </em><em>one mole</em><em> and we also know that </em><em>mass of one mole is given by molar mass.  </em>

<u>Explanation:</u>

b) It is known that 31.98g/mol is the molar mass for oxygen which is greater than that of hydrogen while fluorine has a molar mass of 38.0 g/mol which on comparison shows that, it is the highest amongst all three.

3 0
3 years ago
Which of the following is true of science? (2 points)
Tju [1.3M]

Answer:

It is based on testable and replicable evidence.

7 0
2 years ago
12 *
nikitadnepr [17]

Answer:

true

Explanation:

7 0
3 years ago
The plants shown bloom in summer. Which statement explains why the plants bloom in summer? The nights are shorter. The nights ar
Bess [88]

Answer:

It’s A

Explanation:

The nights are shorter. I just took the unit test review

5 0
3 years ago
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