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adoni [48]
3 years ago
6

Calculate delta Gº for the following system:

Chemistry
1 answer:
Llana [10]3 years ago
7 0

Answer:

ΔG = - 442.5  KJ/mol    

Explanation:

Data Given

delta H = -472 kJ/mol

delta S = -108 J/mol K

So,

delta S = -0.108 J/mol K

delta Gº = ?

Solution:

The answer will be calculated by the following equation for the Gibbs free energy

                    G = H - TS

Where

G = Gibbs free energy

H = enthalpy of a system (heat

T = temperature

S = entropy

So the change in the Gibbs free energy at constant temperature can be written as

                ΔG = ΔH - TΔS . . . . . . (1)

Where

ΔG = Change in Gibb’s free energy

ΔH = Change in enthalpy of a system

ΔS = Change in entropy

if system have standard temperature then

T = 273.15 K

Now,

put values in equation 1

                  ΔG = (-472 kJ/mol) - 273.15 K (-0.108 KJ/mol K)

                 ΔG = (-472 kJ/mol) - (-29.5 KJ/mol)

                 ΔG = -472 kJ/mol + 29.5 KJ/mol

                 ΔG = - 442.5  KJ/mol          

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Answer: Tfinal = 7.1°C

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heat released or absorbed = mass × specific heat capacity × change in temperature

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molar enthalpy of solution, ΔHsoln <em> = heat absorbed or released ÷ moles of solute, </em><em>n</em>

ΔHsoln = q ÷ n

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