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ArbitrLikvidat [17]
3 years ago
9

The standard free energy change for a reaction in an electrolytic cell is always:_________

Chemistry
1 answer:
sattari [20]3 years ago
8 0

Answer: The standard free energy change for a reaction in an electrolytic cell is always positive.

Explanation:

Electrolytic cells use electric currents to drive a non-spontaneous reaction forward.

Relation of standard free energy change and emf of cell

\Delta G^o=-nFE^0_{cell}

where,

\Delta G^o = standard free energy change

  n= no of electrons gained or lost

F= faraday's constant

E^0_{cell} = standard emf

E^0_{cell}   = standard emf = -ve  , for non spontaneous reaction

Thus  \Delta G^o=(-ve)(-ve)=+ve

Thus standard free energy change for a reaction in an electrolytic cell is always positive.

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A strontium hydroxide solution is prepared by dissolving 10.60 gg of Sr(OH)2Sr(OH)2 in water to make 47.00 mLmL of solution.What
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Answer:

Approximately 1.854\; \rm mol\cdot L^{-1}.

Explanation:

Note that both figures in the question come with four significant figures. Therefore, the answer should also be rounded to four significant figures. Intermediate results should have more significant figures than that.

<h3>Formula mass of strontium hydroxide</h3>

Look up the relative atomic mass of \rm Sr, \rm O, and \rm H on a modern periodic table. Keep at least four significant figures in each of these atomic mass data.

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  • \rm O: 15.999.
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Calculate the formula mass of \rm Sr(OH)_2:

M\left(\rm Sr(OH)_2\right) = 87.62 + 2\times (15.999 + 1.008) = 121.634\; \rm g \cdot mol^{-1}.

<h3>Number of moles of strontium hydroxide in the solution</h3>

M\left(\rm Sr(OH)_2\right) =121.634\; \rm g \cdot mol^{-1} means that each mole of \rm Sr(OH)_2 formula units have a mass of 121.634\; \rm g.

The question states that there are 10.60\; \rm g of \rm Sr(OH)_2 in this solution.

How many moles of \rm Sr(OH)_2 formula units would that be?

\begin{aligned}n\left(\rm Sr(OH)_2\right) &= \frac{m\left(\rm Sr(OH)_2\right)}{M\left(\rm Sr(OH)_2\right)}\\ &= \frac{10.60\; \rm g}{121.634\; \rm g \cdot mol^{-1}} \approx 8.71467\times 10^{-2}\; \rm mol\end{aligned}.

<h3>Molarity of this strontium hydroxide solution</h3>

There are 8.71467\times 10^{-2}\; \rm mol of \rm Sr(OH)_2 formula units in this 47\; \rm mL solution. Convert the unit of volume to liter:

V = 47\; \rm mL = 0.047\; \rm L.

The molarity of a solution measures its molar concentration. For this solution:

\begin{aligned}c\left(\rm Sr(OH)_2\right) &= \frac{n\left(\rm Sr(OH)_2\right)}{V}\\ &= \frac{8.71467\times 10^{-2}\; \rm mol}{0.047\; \rm L} \approx 1.854\; \rm mol \cdot L^{-1}\end{aligned}.

(Rounded to four significant figures.)

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