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ArbitrLikvidat [17]
3 years ago
9

The standard free energy change for a reaction in an electrolytic cell is always:_________

Chemistry
1 answer:
sattari [20]3 years ago
8 0

Answer: The standard free energy change for a reaction in an electrolytic cell is always positive.

Explanation:

Electrolytic cells use electric currents to drive a non-spontaneous reaction forward.

Relation of standard free energy change and emf of cell

\Delta G^o=-nFE^0_{cell}

where,

\Delta G^o = standard free energy change

  n= no of electrons gained or lost

F= faraday's constant

E^0_{cell} = standard emf

E^0_{cell}   = standard emf = -ve  , for non spontaneous reaction

Thus  \Delta G^o=(-ve)(-ve)=+ve

Thus standard free energy change for a reaction in an electrolytic cell is always positive.

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2Pb(s) + O2(aq) + 4H+(aq) → 2H2O(l) + 2Pb2+(aq)
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Answer:

The answer to your question is 0.269 g of Pb

Explanation:

Data

Lead solution = 0.000013 M

Volume = 100 L

mass = 0.269 g

atomic mass Pb = 207.2 g

Chemical reaction

                        2Pb(s) + O₂(aq) + 4H⁺(aq) → 2H₂O(l) + 2Pb₂⁺(aq)

Process

1.- Calculate the mass of Pb in solution

Formula

Molarity = \frac{number of moles}{volume}

Solve for number of moles

Number of moles = Volume x Molarity

Substitution

Number of moles = 100 x 0.000013

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2.- Calculate the mass of Pb formed.

                       207.2 g of Pb ----------------- 1 mol

                             x g             ----------------- 0.0013 moles

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