Answer : The equilibrium will shift in the left direction.
Explanation :
Le-Chatelier's principle : This principle states that if any change in the variables of the reaction, the equilibrium will shift in the direction to minimize the effect.
The given reaction is:
As per question, when we are adding 
then the concentration of is increased on product side then the equilibrium will shift in the direction where decrease of concentration of takes place. Therefore, the equilibrium will shift in the left direction.
Thus, the equilibrium will shift in the left direction.
No, why? Cause if you're winding up the clock it's basically doing what it needs to do. So there's no need for batteries.. I hope my sad sentence make sense :p
To determine which order of the reaction it is, first we need to calculate the rate of change of moles.
the data is as follows
time 0 40 80 120 160
moles 0.100 0.067 0.045 0.030 0.020
Q1)
for the first 40 s change of moles ;
= -d[A] / t
= - (0.067-0.100)/40s
= 8.25 x 10⁻⁴ mol/s
for the next 40 s
= -(0.045-0.067)/40
= 5.5 x 10⁻⁴ mol/s
the 40 s after that
= -(0.030-0.045)/40 s
= 3.75 x 10⁻⁴ mol/s
k - rate constant
and A is the only reactant that affects the rate of the reaction
rate = k [A]ᵇ
8.25 × 10⁻⁴ mol/s = k [0.100 mol]ᵇ ----1
5.5 x 10⁻⁴ mol/s = k [0.067 mol]ᵇ -----2
divide the 2nd equation by the 1st equation
1.5 = [1.49]ᵇ
b is almost equal to 1
Therefore this is a first order reaction
Q2)
to find out the rate constant(k), we have to first state the equation for a first order reaction.
rate = k[A]ᵇ
As A is the only reactant thats considered for the rate equation.
Since this is a first order reaction,
b = 1
therefore the reaction is
rate = k[A]
substituting the values,
8.25 x 10⁻⁴ mol/s = k [0.100 mol]
k = 8.25 x 10⁻⁴ mol/s /0.100mol
= 8.25 x 10⁻³ s⁻¹
Grams of Ca(NO₃)₂ produced : 0.985 g
<h3>Further explanation</h3>
A reaction coefficient is a number in the chemical formula of a substance involved in the reaction equation. The reaction coefficient is useful for equalizing reagents and products.
Reaction
CaCl₂ + 2AgNO₃ → 2AgCl + Ca(NO₃)₂
MW AgNO₃ : 107.9+14+3.16=169.9
mol AgNO₃ :
mol ratio Ca(NO₃)₂ : AgNO₃ = 1 : 2, so mol Ca(NO₃)₂ :
MW Ca(NO₃)₂ : 40.1+2.14+6.16=164.1 g/mol
mass Ca(NO₃)₂ :
The poly atomic ion formula for ammonium would be NH4+
