2 is the correct answer because with 2O2 molecules it balances the chemical equation.
Hope that helps
No He believed tiny particles were invisible and couldn't be changed....So No The person that believed in this was Dalton .
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.
The final volume V₂=4.962 L
<h3>Further explanation</h3>
Given
T₁=20 + 273 = 293 K
P₁= 1 atm
V₁ = 4 L
T₂=100+273 = 373 K
P₂=780 torr=1,02632 atm
Required
The final volume
Solution
Combined gas law :
P₁V₁/T₁=P₂V₂/T₂
Input the value :
V₂=(P₁V₁T₂)/(P₂T₁)
V₂=(1 x 4 x 373)/(1.02632 x 293)
V₂=4.962 L
