Answer:
w = -531 kJ
1. Work was done by the system.
Explanation:
Step 1: Given data
- Heat gained by the system (q): 687 kJ (By convention, when the system absorbs heat, q > 0).
- Change in the internal energy of the system (ΔU°): 156 kJ
Step 2: Calculate the work done (w)
We will use the following expression.
ΔU° = q + w
w = ΔU° - q
w = 156 kJ - 687 kJ
w = -531 kJ
By convention, when w < 0, work is done by the system on the surroundings.
The hydrogen and oxygen atoms that combine to form water molecules are bound together by covalent bonds. The electron from the hydrogen splits its time between the incomplete outer shell of the hydrogen atom and the incomplete outer shell of the oxygen atom.