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Oxygen gas can be prepared by heating potassium chlorate according to the following equation:2KClO3(s)Arrow.gif2KCl(s) + 3O2(g)T

Eduardwww [97]

Answer:

Moles of potassium chlorate reacted = 0.2529 moles

The amount of oxygen gas collected will be 12.8675 g

Explanation:

(a)

We are given:

Vapor pressure of water = 17.5 mmHg

Total vapor pressure = 748 mmHg

Vapor pressure of Oxygen gas = Total vapor pressure - Vapor pressure of water = (748 - 17.5) mmHg = 730.5 mmHg

To calculate the amount of Oxygen gas collected, we use the equation given by ideal gas which follows:

$PV=nRT$

where,

P = pressure of the gas = 730.5 mmHg

V = Volume of the gas = 9.49 L

T = Temperature of the gas = $20^oC=[20+273]K=293K$

R = Gas constant = $62.3637\text{ L.mmHg }mol^{-1}K^{-1}$

n = number of moles of oxygen gas = ?

Putting values in above equation, we get:

$730.5mmHg\times 9.49L=n\times 62.3637\text{ L.mmHg }mol^{-1}K^{-1}\times 293K\\\\n=\frac{730.5\times 9.49}{62.3637\times 293}=0.3794mol$

According to the reaction shown below as:-

$2KClO_3(s)\rightarrow 2KCl(s) +3O_2(g)$

3 moles of oxygen gas are produced when 2 moles of potassium chlorate undergoes reaction.

So,

0.3794 mol of oxygen gas are produced when $\frac{2}{3}\times 0.3794$ moles of potassium chlorate undergoes reaction.

<u>Moles of potassium chlorate reacted = 0.2529 moles</u>

(b)

We are given:

Vapor pressure of water = 17.5 mmHg

Total vapor pressure = 753 mmHg

Vapor pressure of Oxygen gas = Total vapor pressure - Vapor pressure of water = (753 - 17.5) mmHg = 735.5 mmHg

To calculate the amount of Oxygen gas collected, we use the equation given by ideal gas which follows:

$PV=nRT$

where,

P = pressure of the gas = 735.5 mmHg

V = Volume of the gas = 9.99 L

T = Temperature of the gas = $20^oC=[20+273]K=293K$

R = Gas constant = $62.3637\text{ L.mmHg }mol^{-1}K^{-1}$

n = number of moles of oxygen gas = ?

Putting values in above equation, we get:

$735.5mmHg\times 9.99L=n\times 62.3637\text{ L.mmHg }mol^{-1}K^{-1}\times 293K\\\\n=\frac{735.5\times 9.99}{62.3637\times 293}=0.40211mol$

Moles of Oxygen gas = 0.40211 moles

Molar mass of Oxygen gas = 32 g/mol

Putting values in above equation, we get:

$0.037mol=\frac{\text{Mass of Oxygen gas}}{2g/mol}\\\\\text{Mass of Oxygen gas}=(0.40211mol\times 32g/mol)=12.8675g$

<u>Hence, the amount of oxygen gas collected will be 12.8675 g</u>

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active,dormant,extinct

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Diffusion is a process that results from the random motion of molecules and results in a net movement of matter from a high-concentration region to a low-concentration zone.

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A compound in a copper ore has the following percentage composition by mass:

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1) since we are given percentages, we can assume we have 100 grams of the molecule.

55.6 % Cu ----> 55.6 grams Cu
16.4 % Fe------> 16.4 grams Fe
28.0% S--------> 28.0 grams S

2) convert each gram to moles using the molar masses given

$55.6 g Cu \frac{1 mol}{63.5 g} = 0.876 mol Cu$
$16.4 g Fe \frac{1 mol}{56.0 g} = 0.293 mol Fe$
$28.0 gS \frac{1 mol}{32.0} = 0.875 mol S$

3) we divide the smallest value of moles (0.293) to each one.

Cu --> 0.876 / 0.293= 3
Fe---> 0.293 / 0.293= 1
S-----> 0.875 / 0.293= 3

4) let's write the empirical formula

Cu₃FeS₃

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