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Answer: 1.14mol
Nitrogen molar mass=14g/mol
N2 molar mass=14*2=28g/mol
31.9g(1/28)=1.14mol N2
Geologists have a rule of thumb: when molten rock cools and solidifies, crystals of compounds with the smallest lattice energies appear at the bottom of the mass because of high power of solubility.
<h3>What is lattice energy? </h3>
The lattice energy is defined as the energy change upon the formation of one mole of crystalline ionic compound from its same constituent ions, that are assumed to be initially in the state of gases. It is also defined as measure of the cohesive forces which bind ionic solids together.
As the lattice energy of the ionic compound increase the solubility of that particular compound decrease. Hence compound which have low lattice energy are more soluble than compound having high lattice energy. When molten rocks cools and solidified, the compound having smallest lattice energy become more soluble than crystals of compound which have large lattice energy. Therefore, crystal of compound with the smallest lattice energy start appearing at the bottom of the mass.
Thus, we concluded that due to high solubility power of compound with low lattice energy appear at the bottom of the mass.
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Q: A
according to this formula, we can get the mole fraction of water (n):
P(solu) = n Pv(water)
when we have Pv(solu) = 22.8 and Pv(water) = 23.8 so by substitution:
22.8 = n * 23.8
n= 0.958
- we need to get the moles of glucose:
moles of water = 500 g(mass weight) / 18 (molar weight)= 27.7 mol
n = moles of water / ( moles of water + moles of glucose)
0.958 = 27.7 / ( 27.7+ moles of glucose)
0.958 moles of glucose + 26.5 = 27.7
0.968 moles of glucose = 1.2
moles of glucose = 1.253 mol
∴ the mass of glucose = no.of glucose moles x molar mass
= 1.253 x 180 = 225.5 g
Q: B
here we also need to get n (mole fraction of water )by using this formula:
Pv(solu) = n Pv(water)
when we have Pv(solu)=132 & Pv(water)=150 so, by substition:
132= n * 150
n = 0.88
so, mole fraction of solution = 1 - 0.88 = 0.12
and we can get after that the moles of water = (mass weight / molar mass)
- no.moles of water = 85 g / 18 g/mol = 4.7 moles
- total moles in solution = moles of water / moles fraction of water
= 4.7 / 0.88 = 5.34 moles
∴ moles of the solution = total moles in solu - moles of water
= 5.34 - 4.7 = 0.64 moles solute
∴ the molar mass of the solute = mass weight of solute / no.of moles of solute
= 53.8 / 0.64 = 84 g/mole
Q: C
moles of urea (NH2)2 CO = mass weight / molar mass
= 4.49 g / 60 g /mol
= 0.07 mol
moles of methanol = mass weight / molar mass
= 39.9 g / 32 g/mol = 1.25 mol
moles fraction of methanol = moles of methanol / (moles of methanol + moles of urea )
moles fraction of methanol = 1.25 / ( 1.25+0.07) = 0.95
by substitution in Pv formula we will be able to get the vapour pressure of the solu :
Pv(solu) = n P°v
Pv(solu) = 0.95 * 89 mm Hg
∴Pv(solu) = 84.55 mmHg
